Teil eines Buches,

The evaporation/condensation transition of Ising droplets

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Abstract Book of the XXIII IUPAP International Conference on Statistical Physics, Genova, Italy, (9-13 July 2007)

Zusammenfassung

In recent analytical work, Biskup et al. Europhys.\ Lett. 60 (2002) 21 studied the behaviour of $d$-dimensional liquid-vapour systems at a fixed excess $N$ of particles above the ambient gas density in the infinite-volume limit. By identifying a dimensionless parameter $\Delta (N)$ and a universal constant $\Delta_c(d)$, they showed that for $\Delta < \Delta_c$ the excess is absorbed in the background (``evaporated'' system), while for $\Delta > \Delta_c$ a droplet of the dense phase occurs (``condensed'' system). Also the fraction $łambda_\Delta$ of excess particles forming the droplet is given explicitly. Furthermore, they argue that the same is true for solid-gas systems. By making use of the well-known equivalence of the lattice-gas picture with the spin-$1/2$ Ising model, we performed Monte Carlo simulations of the Ising model with nearest-neighbour couplings on a square and a triangular lattice with periodic boundary conditions at fixed magnetisation, corresponding to a fixed particles excess. To study the approach to the asymptotic formulas, we measured the largest minority droplet, corresponding to the solid phase, for various system sizes. Using analytic values for the spontaneous magnetisation $m_0$, the susceptibility $\chi$ and the Wulff interfacial free energy density $\tau_W$ for the infinite system, we obtain for both lattice types extrapolations of $łambda_\Delta$ in very good agreement with the theoretical prediction.

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