%0 Generic %1 CanosaMas:1999p3131 %A Canosa-Mas, CE %A Hutton-Squire, HR %A King, MD %A Stewart, DJ %A Thompson, KC %A Wayne, RP %D 1999 %J Journal of Atmospheric Chemistry %K 298 Alkanes, And Atoms, Chlorine Chlorine, Constants, Delta(3)-Carene, Hydrocarbons, Isoprene, K Ketone, Kinetics, Methacrolein Methyl Oh, Rate Vinyl %N 1 %P 163--170 %T Laboratory kinetic studies of the reactions of Cl atoms with species of biogenic origin: Delta(3)-carene, isoprene, methacrolein and methyl vinyl ketone %U http://www.google.com/search?client=safari&rls=en-us&q=Laboratory+kinetic+studies+of+the+reactions+of+Cl+atoms+with+species+of+biogenic+origin:+Delta(3)-carene,+isoprene,+methacrolein+and+methyl+vinyl+ketone&ie=UTF-8&oe=UTF-8 %V 34 %X The rate coefficients for the reaction between atomic chlorine and a number of naturally occurring species have been measured at ambient temperature and atmospheric pressure using the relative rate technique. The values obtained were (4.0 +/- 0.8) x 10(-10), (2.1 +/- 0.5) x 10(-10), (3.2 +/- 0.5) x 10(-10), and (4.9 +/- 0.5) x 10(-10) cm(3) molecule(-1) s(-1), for reactions with isoprene, methyl vinyl ketone, methacrolein and Delta(3)-carene, respectively. The value obtained for isoprene compares favourably with previously reported values. No values have been reported to date for the rate constants of the other reactions.

@proceedingspaper{CanosaMas:1999p3131, abstract = {The rate coefficients for the reaction between atomic chlorine and a number of naturally occurring species have been measured at ambient temperature and atmospheric pressure using the relative rate technique. The values obtained were (4.0 +/- 0.8) x 10(-10), (2.1 +/- 0.5) x 10(-10), (3.2 +/- 0.5) x 10(-10), and (4.9 +/- 0.5) x 10(-10) cm(3) molecule(-1) s(-1), for reactions with isoprene, methyl vinyl ketone, methacrolein and Delta(3)-carene, respectively. The value obtained for isoprene compares favourably with previously reported values. No values have been reported to date for the rate constants of the other reactions.}, added-at = {2010-06-22T19:38:37.000+0200}, affiliation = {Univ Oxford, Phys {\&} Theoret Chem Lab, Oxford OX1 3QZ, England}, author = {Canosa-Mas, CE and Hutton-Squire, HR and King, MD and Stewart, DJ and Thompson, KC and Wayne, RP}, biburl = {https://www.bibsonomy.org/bibtex/2f7fe16d52af885506aa4f20bc183ade1/gsmith}, date-added = {2010-04-28 10:58:46 -0400}, date-modified = {2010-04-28 10:58:51 -0400}, interhash = {90f386f0e827424c385190f26b6aadd6}, intrahash = {f7fe16d52af885506aa4f20bc183ade1}, journal = {Journal of Atmospheric Chemistry}, keywords = {298 Alkanes, And Atoms, Chlorine Chlorine, Constants, Delta(3)-Carene, Hydrocarbons, Isoprene, K Ketone, Kinetics, Methacrolein Methyl Oh, Rate Vinyl}, language = {English}, local-url = {file://localhost/Users/geoffreysmith/Documents/Papers/Journal%20of%20Atmospheric%20Chemistry/1999/Journal%20of%20Atmospheric%20Chemistry,%2034,%20163-170%201999.pdf}, month = Jan, number = 1, pages = {163--170}, pmid = {000082797800012}, rating = {0}, timestamp = {2010-06-22T19:39:25.000+0200}, title = {Laboratory kinetic studies of the reactions of Cl atoms with species of biogenic origin: Delta(3)-carene, isoprene, methacrolein and methyl vinyl ketone}, uri = {papers://E88B624E-D406-46FF-9D95-BB9C1AAE3FDC/Paper/p3131}, url = {http://www.google.com/search?client=safari&rls=en-us&q=Laboratory+kinetic+studies+of+the+reactions+of+Cl+atoms+with+species+of+biogenic+origin:+Delta(3)-carene,+isoprene,+methacrolein+and+methyl+vinyl+ketone&ie=UTF-8&oe=UTF-8}, volume = 34, year = 1999 }