Article,

High-pressure Brillouin scattering from vitreous (Y2O3)(0.27)(P2O5)(0.73)

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PHILOSOPHICAL MAGAZINE B-PHYSICS OF CONDENSED MATTER STATISTICAL MECHANICS ELECTRONIC OPTICAL AND MAGNETIC PROPERTIES, 82 (6): 755-761 (2002)8th International Workshop on Disordered Systems, ANDALO, ITALY, MAR 12-15, 2001.
DOI: 10.1080/13642810110101975

Abstract

Brillouin experiments on vitreous yttrium-phosphate glass under pressures up to 7GPa obtained using a diamond anvil cell are reported, Irreversible changes occur as a function of pressure and are interpreted as an indication of a new polymorph of the original glass. The results are compared with the experimental data available for a series of different glassy systems. The observed Brillouin frequency shift under pressure relative to longitudinal waves is assigned to a rearrangement of PO4 tetrahedra. A mechanism accounting for the pressure-induced transition in glasses is proposed.

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