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A Vector Representation for Thermodynamic Relationships

. Journal of Chemical Education, 83 (1): 155 (2006)
DOI: 10.1021/ed083p155

Abstract

A new method is presented for manipulating thermodynamic relationships that allows the derivation of thermodynamic relationships involving energy-dimensioned potentials, entropy-dimensioned functions, and their natural variables. This approach uses a set of äd hoc" rules that systematize the underlying thermodynamic manipulations. The method is based on uncomplicated matrix algebra and is a representation of the quasi-geometrical method that is based on published thermodynamic diagrams.

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A Vector Representation for Thermodynamic Relationships - Journal of Chemical Education (ACS Publications and Division of Chemical Education)

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