%0 Book Section %1 statphys23_1116 %A Cherif, E. %A Bouanz, M. %B Abstract Book of the XXIII IUPAP International Conference on Statistical Physics %C Genova, Italy %D 2007 %E Pietronero, Luciano %E Loreto, Vittorio %E Zapperi, Stefano %K conductivity critical electrical exponents liquid-liquid mixture phase statphys23 topic-2 transition %T Coexistence curves in Electrical Conductivity of Critical Solution : Isobutyric Acid-Water with Added Ions %U http://st23.statphys23.org/webservices/abstract/preview_pop.php?ID_PAPER=1116 %X Results of comprehensive temperature $(T)$ studies of electrical conductivity ($\sigma$) in the one-and-two regions of the binary fluid mixture of isobutyric acid-water with X MKCl at various critical concentrations are presented. A strong asymmetry of determined coexistence curves causes a strong violation of the law of rectilinear diameter. The obtained critical anomalies in the homegeneous phase $\sigma_crit (T)$ or the diameter of the $\sigma_d (T)$ are associated with the same critical exponent $= 1-0.88$, where $\alpha$ is the specific heat critical exponent. For the mixture with critical composition, the two regions show a concentration behavior with $\sigma_l - \sigma_u |-t|^\beta$. The phase-transition region shifts as a function of the salt concentration . The effective-critical exponent $\beta^* = ( 0.264-0.296)$ is neither compatible with the Ising value $= 0.325$ nor with the Fisher renormalized value $0.365$.

@incollection{statphys23_1116, abstract = {Results of comprehensive temperature $(T)$ studies of electrical conductivity ($\sigma$) in the one-and-two regions of the binary fluid mixture of isobutyric acid-water with X M[KCl] at various critical concentrations are presented. A strong asymmetry of determined coexistence curves causes a strong violation of the law of rectilinear diameter. The obtained critical anomalies in the homegeneous phase $\sigma_{crit} (T)$ or the diameter of the $\sigma_d (T)$ are associated with the same critical exponent $\theta = 1-\alpha \sim 0.88$, where $\alpha$ is the specific heat critical exponent. For the mixture with critical composition, the two regions show a concentration behavior with $\sigma_l - \sigma_u \sim {|-t|}^{\beta}$. The phase-transition region shifts as a function of the salt concentration . The effective-critical exponent $\beta^* = ( 0.264-0.296)$ is neither compatible with the Ising value $\beta = 0.325$ nor with the Fisher renormalized value $\sim 0.365$.}, added-at = {2007-06-20T10:16:09.000+0200}, address = {Genova, Italy}, author = {Cherif, E. and Bouanz, M.}, biburl = {https://www.bibsonomy.org/bibtex/264a18721fd40f4d4a85a4f8657e72a91/statphys23}, booktitle = {Abstract Book of the XXIII IUPAP International Conference on Statistical Physics}, editor = {Pietronero, Luciano and Loreto, Vittorio and Zapperi, Stefano}, interhash = {01aa4338390f64d536f85fcf99f0d292}, intrahash = {64a18721fd40f4d4a85a4f8657e72a91}, keywords = {conductivity critical electrical exponents liquid-liquid mixture phase statphys23 topic-2 transition}, month = {9-13 July}, timestamp = {2007-06-20T10:16:39.000+0200}, title = {Coexistence curves in Electrical Conductivity of Critical Solution : Isobutyric Acid-Water with Added Ions}, url = {http://st23.statphys23.org/webservices/abstract/preview_pop.php?ID_PAPER=1116}, year = 2007 }