%0 Journal Article %1 Kumar2012 %A Kumar, Bharat %A Viboh, Ruth L. %A Bonifacio, Margel C. %A Thompson, William B. %A Buttrick, Jonathan C. %A Westlake, Babe C. %A Kim, Min-Soo %A Zoellner, Robert W. %A Varganov, Sergey A. %A Mörschel, Philipp %A Teteruk, Jaroslav %A Schmidt, Martin U. %A King, Benjamin T. %D 2012 %I WILEY-VCH Verlag %J Angew. Chem. Int. Ed. %K aromatic-hydrocarbon aromaticity fused-ring-systems kekulenes macrocycles metathesis septulene %N 51 %P 12795--12800 %R 10.1002/anie.201203266 %T Septulene: The Heptagonal Homologue of Kekulene %U http://dx.doi.org/10.1002/anie.201203266 %V 51 %X A family likeness: The seven-sided homologue of kekulene, septulene (see structure), has been synthesized in seven steps by ring-closing metathesis. Its properties (spectroscopic and structural) are strikingly similar to those of kekulene despite its sevenfold symmetry and resulting non-alternant structure. The chair-type conformation in the crystal arises from packing forces. Septulene is probably a free pseudorotor in the gas phase.

@article{Kumar2012, abstract = {{A family likeness: The seven-sided homologue of kekulene, septulene (see structure), has been synthesized in seven steps by ring-closing metathesis. Its properties (spectroscopic and structural) are strikingly similar to those of kekulene despite its sevenfold symmetry and resulting non-alternant structure. The chair-type conformation in the crystal arises from packing forces. Septulene is probably a free pseudorotor in the gas phase.}}, added-at = {2019-03-11T21:00:05.000+0100}, author = {Kumar, Bharat and Viboh, Ruth L. and Bonifacio, Margel C. and Thompson, William B. and Buttrick, Jonathan C. and Westlake, Babe C. and Kim, Min-Soo and Zoellner, Robert W. and Varganov, Sergey A. and M\"{o}rschel, Philipp and Teteruk, Jaroslav and Schmidt, Martin U. and King, Benjamin T.}, biburl = {https://www.bibsonomy.org/bibtex/20270ce433c226ff3e5d92534f9ca44bf/fairybasslet}, citeulike-article-id = {11465733}, citeulike-linkout-0 = {http://dx.doi.org/10.1002/anie.201203266}, day = 14, doi = {10.1002/anie.201203266}, interhash = {3aaf8d89371093f18ec6fda22d39e28e}, intrahash = {0270ce433c226ff3e5d92534f9ca44bf}, issn = {1433-7851}, journal = {Angew. Chem. Int. Ed.}, keywords = {aromatic-hydrocarbon aromaticity fused-ring-systems kekulenes macrocycles metathesis septulene}, month = dec, number = 51, pages = {12795--12800}, posted-at = {2013-09-20 14:05:16}, priority = {2}, publisher = {WILEY-VCH Verlag}, timestamp = {2019-03-11T21:06:37.000+0100}, title = {{Septulene: The Heptagonal Homologue of Kekulene}}, url = {http://dx.doi.org/10.1002/anie.201203266}, volume = 51, year = 2012 }