%0 Journal Article %1 doi:10.1021/ct300902c %A Limacher, Peter A. %A Ayers, Paul W. %A Johnson, Paul A. %A De Baerdemacker, Stijn %A Van Neck, Dimitri %A Bultinck, Patrick %D 2013 %J Journal of Chemical Theory and Computation %K chemistry density fock functional hartree quantum theory unread %N 3 %P 1394-1401 %R 10.1021/ct300902c %T A New Mean-Field Method Suitable for Strongly Correlated Electrons: Computationally Facile Antisymmetric Products of Nonorthogonal Geminals %U http://pubs.acs.org/doi/abs/10.1021/ct300902c %V 9 %X We propose an approach to the electronic structure problem based on noninteracting electron pairs that has similar computational cost to conventional methods based on noninteracting electrons. In stark contrast to other approaches, the wave function is an antisymmetric product of nonorthogonal geminals, but the geminals are structured so the projected Schrödinger equation can be solved very efficiently. We focus on an approach where, in each geminal, only one of the orbitals in a reference Slater determinant is occupied. The resulting method gives good results for atoms and small molecules. It also performs well for a prototypical example of strongly correlated electronic systems, the hydrogen atom chain.

@article{doi:10.1021/ct300902c, abstract = { We propose an approach to the electronic structure problem based on noninteracting electron pairs that has similar computational cost to conventional methods based on noninteracting electrons. In stark contrast to other approaches, the wave function is an antisymmetric product of nonorthogonal geminals, but the geminals are structured so the projected Schrödinger equation can be solved very efficiently. We focus on an approach where, in each geminal, only one of the orbitals in a reference Slater determinant is occupied. The resulting method gives good results for atoms and small molecules. It also performs well for a prototypical example of strongly correlated electronic systems, the hydrogen atom chain. }, added-at = {2013-03-27T15:44:44.000+0100}, author = {Limacher, Peter A. and Ayers, Paul W. and Johnson, Paul A. and De Baerdemacker, Stijn and Van Neck, Dimitri and Bultinck, Patrick}, biburl = {https://www.bibsonomy.org/bibtex/218abb7d8b0841b0d855bb2fb3dd055d8/drmatusek}, doi = {10.1021/ct300902c}, eprint = {http://pubs.acs.org/doi/pdf/10.1021/ct300902c}, interhash = {810e2935ae03489bd1524911d8873355}, intrahash = {18abb7d8b0841b0d855bb2fb3dd055d8}, journal = {Journal of Chemical Theory and Computation}, keywords = {chemistry density fock functional hartree quantum theory unread}, month = mar, number = 3, pages = {1394-1401}, timestamp = {2013-03-27T15:44:44.000+0100}, title = {A New Mean-Field Method Suitable for Strongly Correlated Electrons: Computationally Facile Antisymmetric Products of Nonorthogonal Geminals}, url = {http://pubs.acs.org/doi/abs/10.1021/ct300902c}, volume = 9, year = 2013 }