%0 Journal Article %1 WOS:000363355200029 %A Marques, Thalles M F %A Ferreira, Odair P %A da Costa, Jose A P %A Fujisawa, Kazunori %A Terrones, Mauricio %A Viana, Bartolomeu C %C THE BOULEVARD, LANGFORD LANE, KIDLINGTON, OXFORD OX5 1GB, ENGLAND %D 2015 %I PERGAMON-ELSEVIER SCIENCE LTD %J JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS %K CeO2} Ion Nanoparticles decoration; exchanging; nanotubes; {Titanate %P 213-220 %R 10.1016/j.jpcs.2015.08.022 %T Study of the growth of CeO2 nanoparticles onto titanate nanotubes %V 87 %X We report the study of the growth of CeO2 nanoparticles on the external walls and Ce4+ intercalation within the titanate nanotubes. The materials were fully characterized by multiple techniques, such as: Raman spectroscopy, infrared spectroscopy (FTIR), energy dispersive spectroscopy (EDS), X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS) and transmission electron microscopy (TEM). The ion exchange processes in the titanate nanotubes were carried out using different concentrations of Ce4+ in aqueous solution. Our results indicate that the growth of CeO2 nanoparticles grown mediated by the hydrolysis in the colloidal species of Ce and the attachment onto the titanate nanotubes happened and get it strongly anchored to the titanate nanotube surface by a simple electrostatic interaction between the nanoparticles and titanate nanotubes, which can explain the small size and even distribution of nanoparticies on titanate supports. It was demonstrated that it is possible to control the amount and size of CeO2 nanoparticles onto the nanotube surface, the species of the Ce ions intercalated between the layers of titanate nanotubes, and the materials could be tuned for using in specific catalysis in according with the amount of CeO2 nanoparticles, their oxygen vacancies/defects and the types of Ce species (Ce4+ or Ce3+) present into the nanotubes. (C) 2015 Elsevier Ltd. All rights reserved.

@article{WOS:000363355200029, abstract = {We report the study of the growth of CeO2 nanoparticles on the external walls and Ce4+ intercalation within the titanate nanotubes. The materials were fully characterized by multiple techniques, such as: Raman spectroscopy, infrared spectroscopy (FTIR), energy dispersive spectroscopy (EDS), X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS) and transmission electron microscopy (TEM). The ion exchange processes in the titanate nanotubes were carried out using different concentrations of Ce4+ in aqueous solution. Our results indicate that the growth of CeO2 nanoparticles grown mediated by the hydrolysis in the colloidal species of Ce and the attachment onto the titanate nanotubes happened and get it strongly anchored to the titanate nanotube surface by a simple electrostatic interaction between the nanoparticles and titanate nanotubes, which can explain the small size and even distribution of nanoparticies on titanate supports. It was demonstrated that it is possible to control the amount and size of CeO2 nanoparticles onto the nanotube surface, the species of the Ce ions intercalated between the layers of titanate nanotubes, and the materials could be tuned for using in specific catalysis in according with the amount of CeO2 nanoparticles, their oxygen vacancies/defects and the types of Ce species (Ce4+ or Ce3+) present into the nanotubes. (C) 2015 Elsevier Ltd. All rights reserved.}, added-at = {2022-05-23T20:00:14.000+0200}, address = {THE BOULEVARD, LANGFORD LANE, KIDLINGTON, OXFORD OX5 1GB, ENGLAND}, author = {Marques, Thalles M F and Ferreira, Odair P and da Costa, Jose A P and Fujisawa, Kazunori and Terrones, Mauricio and Viana, Bartolomeu C}, biburl = {https://www.bibsonomy.org/bibtex/236cccd97b790435aa00c5565e7a901eb/ppgfis_ufc_br}, doi = {10.1016/j.jpcs.2015.08.022}, interhash = {82015b876e5a43a14e4586dec3ba33be}, intrahash = {36cccd97b790435aa00c5565e7a901eb}, issn = {0022-3697}, journal = {JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS}, keywords = {CeO2} Ion Nanoparticles decoration; exchanging; nanotubes; {Titanate}, pages = {213-220}, publisher = {PERGAMON-ELSEVIER SCIENCE LTD}, pubstate = {published}, timestamp = {2022-05-23T20:00:14.000+0200}, title = {Study of the growth of CeO2 nanoparticles onto titanate nanotubes}, tppubtype = {article}, volume = 87, year = 2015 }