%0 Journal Article %1 AENM:AENM201602509 %A An, Mingwei %A Xie, Fangyuan %A Geng, Xinjian %A Zhang, Jianqi %A Jiang, Jiaxing %A Lei, Zhongli %A He, Dan %A Xiao, Zuo %A Ding, Liming %D 2017 %J Advanced Energy Materials %K additionally new_material organic processing %P n/a--n/a %R 10.1002/aenm.201602509 %T A High-Performance D–A Copolymer Based on Dithieno3,2-b:2′,3′-dPyridin-5(4H)-One Unit Compatible with Fullerene and Nonfullerene Acceptors in Solar Cells %U http://dx.doi.org/10.1002/aenm.201602509 %X Development of high-performance donor–acceptor (D–A) copolymers is vital in the research of polymer solar cells (PSCs). In this work, a low-bandgap D–A copolymer based on dithieno3,2-b:2′,3′-dpyridin-5(4H)-one unit (DTP), PDTP4TFBT, is developed and used as the donor material for PSCs with PC71BM or ITIC as the acceptor. PDTP4TFBT:PC71BM and PDTP4TFBT:ITIC solar cells give power conversion efficiencies (PCEs) up to 8.75% and 7.58%, respectively. 1,8-Diiodooctane affects film morphology and device performance for fullerene and nonfullerene solar cells. It inhibits the active materials from forming large domains and improves PCE for PDTP4TFBT:PC71BM cells, while it promotes the aggregation and deteriorates performance for PDTP4TFBT:ITIC cells. The ternary-blend cells based on PDTP4TFBT:PC71BM:ITIC (1:1.2:0.3) give a decent PCE of 9.20%.

@article{AENM:AENM201602509, abstract = {Development of high-performance donor–acceptor (D–A) copolymers is vital in the research of polymer solar cells (PSCs). In this work, a low-bandgap D–A copolymer based on dithieno[3,2-b:2′,3′-d]pyridin-5(4H)-one unit (DTP), PDTP4TFBT, is developed and used as the donor material for PSCs with PC71BM or ITIC as the acceptor. PDTP4TFBT:PC71BM and PDTP4TFBT:ITIC solar cells give power conversion efficiencies (PCEs) up to 8.75% and 7.58%, respectively. 1,8-Diiodooctane affects film morphology and device performance for fullerene and nonfullerene solar cells. It inhibits the active materials from forming large domains and improves PCE for PDTP4TFBT:PC71BM cells, while it promotes the aggregation and deteriorates performance for PDTP4TFBT:ITIC cells. The ternary-blend cells based on PDTP4TFBT:PC71BM:ITIC (1:1.2:0.3) give a decent PCE of 9.20%.}, added-at = {2017-04-19T11:16:52.000+0200}, author = {An, Mingwei and Xie, Fangyuan and Geng, Xinjian and Zhang, Jianqi and Jiang, Jiaxing and Lei, Zhongli and He, Dan and Xiao, Zuo and Ding, Liming}, biburl = {https://www.bibsonomy.org/bibtex/2e70bd8a5f5296c1e21f20d6e4b56a8bb/bretschneider_m}, doi = {10.1002/aenm.201602509}, interhash = {9d239ed9d69425564805988e49354b7e}, intrahash = {e70bd8a5f5296c1e21f20d6e4b56a8bb}, issn = {1614-6840}, journal = {Advanced Energy Materials}, keywords = {additionally new_material organic processing}, pages = {n/a--n/a}, timestamp = {2017-04-19T11:16:52.000+0200}, title = {A High-Performance D–A Copolymer Based on Dithieno[3,2-b:2′,3′-d]Pyridin-5(4H)-One Unit Compatible with Fullerene and Nonfullerene Acceptors in Solar Cells}, url = {http://dx.doi.org/10.1002/aenm.201602509}, year = 2017 }