A new bispyrenyl azadiene derivative has been synthesized and examined for its cation recognition abilities toward different cations. The ligand shows strong affinity for Hg2+ ions over other cations such as Cu2+, Pb2+, Zn2+, Ni2+, Cd2+, Ag+, K+, Na+ and Li+. An Öff-On" type of fluorescent behaviour was observed with simultaneous presence of Cu2+ and Hg2+ ions. An ion selective electrode (ISE) is also formed which showed excellent selectivity to Hg2+ over all the other cations tested. The lower limit of detection is 7.08 times 10-6 M.
%0 Journal Article
%1 Kumar2010
%A Kumar, Manoj
%A Dhir, Abhimanew
%A Bhalla, Vandana
%A Sharma, Richa
%A Puri, Rajiv K.
%A Mahajan, Rakesh K.
%D 2010
%I The Royal Society of Chemistry
%J Analyst
%K 6410 fluorescence sensing
%P 1600-1605
%R 10.1039/b922072k
%T Highly effective chemosensor for mercury ions based on bispyrenyl derivative
%U http://dx.doi.org/10.1039/b922072k
%V 135
%X A new bispyrenyl azadiene derivative has been synthesized and examined for its cation recognition abilities toward different cations. The ligand shows strong affinity for Hg2+ ions over other cations such as Cu2+, Pb2+, Zn2+, Ni2+, Cd2+, Ag+, K+, Na+ and Li+. An Öff-On" type of fluorescent behaviour was observed with simultaneous presence of Cu2+ and Hg2+ ions. An ion selective electrode (ISE) is also formed which showed excellent selectivity to Hg2+ over all the other cations tested. The lower limit of detection is 7.08 times 10-6 M.
@article{Kumar2010,
abstract = {A new bispyrenyl azadiene derivative has been synthesized and examined for its cation recognition abilities toward different cations. The ligand shows strong affinity for Hg2+ ions over other cations such as Cu2+, Pb2+, Zn2+, Ni2+, Cd2+, Ag+, K+, Na+ and Li+. An "Off-On" type of fluorescent behaviour was observed with simultaneous presence of Cu2+ and Hg2+ ions. An ion selective electrode (ISE) is also formed which showed excellent selectivity to Hg2+ over all the other cations tested. The lower limit of detection is 7.08 [times] 10-6 M.},
added-at = {2011-10-01T00:56:41.000+0200},
author = {Kumar, Manoj and Dhir, Abhimanew and Bhalla, Vandana and Sharma, Richa and Puri, Rajiv K. and Mahajan, Rakesh K.},
biburl = {https://www.bibsonomy.org/bibtex/25a56425c64694bd56bf42523bbdfde0c/afcallender},
citeulike-article-id = {7128683},
citeulike-linkout-0 = {http://dx.doi.org/10.1039/b922072k},
citeulike-linkout-1 = {http://www.rsc.org/Publishing/Journals/article.asp?doi=b922072k},
doi = {10.1039/b922072k},
file = {Kumar2010.pdf:indexed\\Kumar2010.pdf:PDF},
groups = {public},
interhash = {ffeb3fca9965b13bd6d4227259c095d2},
intrahash = {5a56425c64694bd56bf42523bbdfde0c},
journal = {Analyst},
keywords = {6410 fluorescence sensing},
pages = {1600-1605},
posted-at = {2010-05-05 13:33:39},
priority = {2},
publisher = {The Royal Society of Chemistry},
timestamp = {2011-10-01T00:56:41.000+0200},
title = {Highly effective chemosensor for mercury ions based on bispyrenyl derivative},
url = {http://dx.doi.org/10.1039/b922072k},
username = {afcallender},
volume = 135,
year = 2010
}