Abstract
For the first time we present analytical results for the contribution of
electromagnetic fluctuations into thermodynamic properties of modulated
systems, like cholesteric or smectic liquid crystalline films. In the case of
small dielectric anisotropy we have derived explicit analytical expressions for
the chemical potential of such systems. Two limiting cases were specifically
considered: (i) the Van der Waals (VdW) limit, i.e., in the case when the
retardation of the electromagnetic interactions can be neglected; and (ii) the
Casimir limit, i.e. when the effects of retardation becomes considerable. It
was shown that in the Casimir limit, the film chemical potential oscillates
with the thickness of the film. This non-monotonic dependence of the chemical
potential on the film thickness can lead to step-wise wetting phenomena,
surface anchoring reorientation and other important effects. Applications of
the results may concern the various systems in soft matter or condensed matter
physics with multilayer or modulated structures.
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