%0 Journal Article %1 WOS:A1990EQ22100006 %A MCGREAVY, C %A ANDRADE, JS %A RAJAGOPAL, K %C PO BOX 5829, W-6200 WIESBADEN 1, GERMANY %D 1990 %I FRIEDR VIEWEG SOHN VERLAG GMBH %J CHROMATOGRAPHIA %K BAND BROADENING} CHROMATOGRAPHY; EXCLUSION MODEL; NETWORK {SIZE %N 11-12 %P 639-644 %R 10.1007/BF02269738 %T SIZE EXCLUSION CHROMATOGRAPHY IN PORE NETWORKS %V 30 %X A network model is proposed to describe the intraparticle porous structure of an SEC (size exclusion chromatography) column and solved using orthogonal collocation. Comparison of the retention and band broadening features with the conventional model of a parallel bundle of capillaries shows significant differences, which demonstrate the importance of including morphological characteristics into the model to account for the mass transfer restrictions.

@article{WOS:A1990EQ22100006, abstract = {A network model is proposed to describe the intraparticle porous structure of an SEC (size exclusion chromatography) column and solved using orthogonal collocation. Comparison of the retention and band broadening features with the conventional model of a parallel bundle of capillaries shows significant differences, which demonstrate the importance of including morphological characteristics into the model to account for the mass transfer restrictions.}, added-at = {2022-05-23T20:00:14.000+0200}, address = {PO BOX 5829, W-6200 WIESBADEN 1, GERMANY}, author = {MCGREAVY, C and ANDRADE, JS and RAJAGOPAL, K}, biburl = {https://www.bibsonomy.org/bibtex/23c79c4ec821e9b93a9959743af593381/ppgfis_ufc_br}, doi = {10.1007/BF02269738}, interhash = {86fe945924f26ac858bb570f125fb241}, intrahash = {3c79c4ec821e9b93a9959743af593381}, issn = {0009-5893}, journal = {CHROMATOGRAPHIA}, keywords = {BAND BROADENING} CHROMATOGRAPHY; EXCLUSION MODEL; NETWORK {SIZE}, number = {11-12}, pages = {639-644}, publisher = {FRIEDR VIEWEG SOHN VERLAG GMBH}, pubstate = {published}, timestamp = {2022-05-23T20:00:14.000+0200}, title = {SIZE EXCLUSION CHROMATOGRAPHY IN PORE NETWORKS}, tppubtype = {article}, volume = 30, year = 1990 }