%0 Journal Article %1 Duan2003 %A Duan, Zhenhao %A Sun, Rui %D 2003 %J Chemical Geology %K 2003 CO2 NaCl aqueous modelling seawater solubility thermodynamic water %N 3-4 %P 257 - 271 %R 10.1016/S0009-2541(02)00263-2 %T An improved model calculating CO2 solubility in pure water and aqueous NaCl solutions from 273 to 533 K and from 0 to 2000 bar %U http://dx.doi.org/10.1016/S0009-2541(02)00263-2 %V 193 %X A thermodynamic model for the solubility of carbon dioxide (CO2) in pure water and in aqueous NaCl solutions for temperatures from 273 to 533 K, for pressures from 0 to 2000 bar, and for ionic strength from 0 to 4.3 m is presented. The model is based on a specific particle interaction theory for the liquid phase and a highly accurate equation of state for the vapor phase. With this specific interaction approach, this model is able to predict CO2 solubility in other systems, such as CO2-H2O-CaCl2 and CO2-seawater, without fitting experimental data from these systems. Comparison of the model predictions with experimental data indicates that the model is within or close to experimental uncertainty, which is about 7\% in CO2 solubility.

@article{Duan2003, abstract = {A thermodynamic model for the solubility of carbon dioxide (CO2) in pure water and in aqueous NaCl solutions for temperatures from 273 to 533 K, for pressures from 0 to 2000 bar, and for ionic strength from 0 to 4.3 m is presented. The model is based on a specific particle interaction theory for the liquid phase and a highly accurate equation of state for the vapor phase. With this specific interaction approach, this model is able to predict CO2 solubility in other systems, such as CO2-H2O-CaCl2 and CO2-seawater, without fitting experimental data from these systems. Comparison of the model predictions with experimental data indicates that the model is within or close to experimental uncertainty, which is about 7\% in CO2 solubility.}, added-at = {2011-01-19T18:05:51.000+0100}, author = {Duan, Zhenhao and Sun, Rui}, biburl = {https://www.bibsonomy.org/bibtex/2d819443ec671238d0da34e4b2608c5e4/thorade}, description = {ScienceDirect - Chemical Geology : An improved model calculating CO2 solubility in pure water and aqueous NaCl solutions from 273 to 533 K and from 0 to 2000 bar}, doi = {10.1016/S0009-2541(02)00263-2}, interhash = {a81b69f2f73b6b8a2fe2d8efc3ef53d8}, intrahash = {d819443ec671238d0da34e4b2608c5e4}, issn = {0009-2541}, journal = {Chemical Geology}, keywords = {2003 CO2 NaCl aqueous modelling seawater solubility thermodynamic water}, number = {3-4}, pages = {257 - 271}, timestamp = {2011-07-21T11:42:29.000+0200}, title = {An improved model calculating CO2 solubility in pure water and aqueous NaCl solutions from 273 to 533 K and from 0 to 2000 bar}, url = {http://dx.doi.org/10.1016/S0009-2541(02)00263-2}, volume = 193, year = 2003 }