%0 Journal Article %1 Mao2010 %A Mao, Shide %A Duan, Zhenhao %A Hu, Jiawen %A Zhang, Dehui %D 2010 %J Chemical Geology %K water equation-of-state CO2 brine 2010 NaCl Helmholtz geofluid %N 3-4 %P 148 - 160 %R 10.1016/j.chemgeo.2010.05.004 %T A model for single-phase PVTx properties of CO2-CH4-C2H6-N2-H2O-NaCl fluid mixtures from 273 to 1273 K and from 1 to 5000 bar %U http://dx.doi.org/10.1016/j.chemgeo.2010.05.004 %V 275 %X A thermodynamic model explicit in Helmholtz free energy is constructed to calculate the single-phase PVTx properties of the CO2-CH4-C2H6-N2-H2O fluid mixtures. Parameters of the binary CO2-H2O, CH4-H2O, C2H6-H2O and N2-H2O mixtures are regressed from assessed experimental data. On the basis of the binary mixture parameters, the model can be used to predict the single-phase volumes of the CO2-CH4-C2H6-N2-H2O-NaCl fluid mixtures with a simple approach. Comparison with a large number of experimental data shows that the model can reproduce the single-phase PVTx properties of the CO2-CH4-C2H6-N2-H2O-NaCl fluid mixtures from 273 to 1273 K and from 1 to 5000 bar, with or close to experimental accuracy. Online calculations can be made on the website: www.geochem-model.org/.

@article{Mao2010, abstract = {A thermodynamic model explicit in Helmholtz free energy is constructed to calculate the single-phase PVTx properties of the CO2-CH4-C2H6-N2-H2O fluid mixtures. Parameters of the binary CO2-H2O, CH4-H2O, C2H6-H2O and N2-H2O mixtures are regressed from assessed experimental data. On the basis of the binary mixture parameters, the model can be used to predict the single-phase volumes of the CO2-CH4-C2H6-N2-H2O-NaCl fluid mixtures with a simple approach. Comparison with a large number of experimental data shows that the model can reproduce the single-phase PVTx properties of the CO2-CH4-C2H6-N2-H2O-NaCl fluid mixtures from 273 to 1273 K and from 1 to 5000 bar, with or close to experimental accuracy. Online calculations can be made on the website: www.geochem-model.org/.}, added-at = {2011-01-19T18:06:52.000+0100}, author = {Mao, Shide and Duan, Zhenhao and Hu, Jiawen and Zhang, Dehui}, biburl = {https://www.bibsonomy.org/bibtex/2cd7512123d02ab61528fa47914d164a9/thorade}, description = {ScienceDirect - Chemical Geology : A model for single-phase PVTx properties of CO2–CH4–C2H6–N2–H2O–NaCl fluid mixtures from 273 to 1273 K and from 1 to 5000 bar}, doi = {10.1016/j.chemgeo.2010.05.004}, interhash = {ed65b34587fb3c3df66f994cecb868e7}, intrahash = {cd7512123d02ab61528fa47914d164a9}, issn = {0009-2541}, journal = {Chemical Geology}, keywords = {water equation-of-state CO2 brine 2010 NaCl Helmholtz geofluid}, number = {3-4}, pages = {148 - 160}, timestamp = {2011-01-19T18:06:52.000+0100}, title = {A model for single-phase PVTx properties of CO2-CH4-C2H6-N2-H2O-NaCl fluid mixtures from 273 to 1273 K and from 1 to 5000 bar}, url = {http://dx.doi.org/10.1016/j.chemgeo.2010.05.004}, volume = 275, year = 2010 }