Artikel,

Gold Nanoparticles: Assembly, Supramolecular Chemistry, Quantum-Size-Related Properties and Applications toward Biology, Catalysis and Nanotechnology

, und .
Chemical Reviews, (2004)
DOI: 10.1021/cr030698+

Zusammenfassung

1. Historic Introduction 2. General Background: Quantum Size Effect and Single-Electron Transitions 3. Synthesis and Assembly 3.1. Citrate Reduction 3.2. The Brust−Schiffrin Method: Two-Phase Synthesis and Stabilization by Thiols 3.3. Other Sulfur Ligands 3.4. Other Ligands3.4.1. Phosphine, Phosphine Oxide, Amine, and Carboxylate Ligands 3.4.2. Isocyanide 3.4.3. Acetone 3.4.4. Iodine 3.5. Microemulsion, Reversed Micelles, Surfactants, Membranes, and Polyelectrolytes 3.6. Seeding Growth 3.7. Physical Methods: Photochemistry (UV, Near-IR), Sonochemistry, Radiolysis, and Thermolysis 3.8. Solubilization in Fluorous and Aqueous Media 3.9. Characterization Techniques 3.10. Bimetallic Nanoparticles 3.11. Polymers 3.12. Dendrimers 3.13. Surfaces, Films, Silica, and Other AuNP Materials 4. Physical Properties 4.1. The Surface Plasmon Band (SPB) 4.2. Fluorescence 4.3. Electrochemistry 4.4. Electronic Properties Using Other Physical Methods 5. Chemical, Supramolecular, and Recognition Properties 5.1. Reactions of Thiolate-Stabilized AuNPs 5.2. Supramolecular Chemistry 5.3. Molecular Recognition5.3.1. Redox Recognition Using Functionalized AuNPs as Exoreceptors 5.3.2. Miscellaneous Recognition and Sensors 6. Biology 6.1. DNA−AuNPs Assemblies and Sensors 6.2. AuNP-Enhanced Immuno-Sensing 6.3. AuNP Sugar Sensors 6.4. Other AuNP Bioconjugates: Peptides, Lipids, Enzymes, Drugs, and Viruses 6.5. AuNP Biosynthesis 7. Catalysis 7.1. Catalysis of CO Oxidation 7.2. Electrochemical Redox Catalysis of CO and CH3OH Oxidation and O2 Reduction 7.3. Catalysis of Hydrogenation of Unsaturated Substrates 7.4. Catalysis by Functional Thiolate-Stabilized AuNPs 7.5. Other Types of Catalysis 8. Nonlinear Optics (NLO) 9. Miscellaneous Applications 10. Conclusion and Perspectives 11. Acknowledgment 12. Abbreviations 13. References

Tags

Nutzer

  • @afcallender

Kommentare und Rezensionen