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Confinement-induced enhancement of diffusiophoretic forces on self-propellers

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Abstract Book of the XXIII IUPAP International Conference on Statistical Physics, Genova, Italy, (9-13 July 2007)

Аннотация

For applications in, e.g., drug-delivery systems or micromechanics, one of the most challenging problems at this stage is to develop ways to enable small-scale objects to perform autonomous, controlled motion. Exploiting a variety of physical and chemical processes, a number of ``proof of principle'' proposals of such micro-engines have been made (for both translational and rotational motion). Employing as a working example a recently proposed simple model of a self-propelling device driven by chemical reactions taking place on some parts of its surface 1, we study the effect of spatial confinement on the magnitude of propulsive diffusiophoretic forces acting on such a particle. We demonstrate that the motive force significantly increases in the presence of confining walls, even in the case of the simplest possible confining geometry, that is, of a wall with the same shape as the particle, and we also show that such effects become even more pronounced in two-dimensional systems. We further present numerical results for the technologically relevant case of a spherical particles within a cylindrical pore. References:\\ 1) Golestanian R., Liverpool T. B., and Ajdari A., Phys. Rev. Lett. 94, 220801 (2005).

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