Artikel,

Quantum Defects of the n2P1/2,3/2 Levels in 39K I and 85Rb I

, und .
Phys. Scr., 27 (4): 300-305 (1983)

Zusammenfassung

The energies of the n2P1/2,3/2 level series in 39K (9 ? n ? 21) and 85Rb (13 ? n ? 68) have been measured using frequency-doubled cw dye las er radiation, a thermionic detector and a high-precision vacuum-wavemeter. By me ans of a Rydberg-Ritz fitting procedure accurate quantum defect data and ionizat ion limits are given. The ionization limits are in agreement with the limits der ived from energy data of other l-series which have been measured recently with l aser spectroscopy techniques. The compact Rydberg-Ritz formulas can serve as han dy secondary wavelength standards with high precision. A compilation of the most accurate Rydberg-Ritz coefficient of all alkali term series with l ? 3 is pre sented and the present status of alkali quantum defect data is discussed. This s et of data includes also recent measurements of 133Cs n2S1/2 and n2D3/2,5/2 leve ls and of some low-lying 7Li levels.

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