%0 Journal Article %1 MARC:MARC201300269 %A Gangloff, Niklas %A Fetsch, Corinna %A Luxenhofer, Robert %D 2013 %I WILEY-VCH Verlag %J Macromolecular Rapid Communications %K living opening polymerization polypeptoids ring rluxenhofer %N 12 %P 997--1001 %R 10.1002/marc.201300269 %T Polypeptoids by Living Ring-Opening Polymerization of N-Substituted N-Carboxyanhydrides from Solid Supports %U http://dx.doi.org/10.1002/marc.201300269 %V 34 %X The nucleophilic living ring-opening polymerization of N-substituted glycine N-carboxyanhydrides using solid-phase synthesis resins is reported. By variation of experimental parameters, products with near Poisson distributions are obtained. As opposed to reversible deactivation radical polymerization, the living polymerization is demonstrated to be viable to high monomer conversion and through multiple monomer addition steps. Successful preparation of a multiblock copolypeptoid is proof for a highly living and robust character of the solid-phase peptoid polymerization.

@article{MARC:MARC201300269, abstract = {The nucleophilic living ring-opening polymerization of N-substituted glycine N-carboxyanhydrides using solid-phase synthesis resins is reported. By variation of experimental parameters, products with near Poisson distributions are obtained. As opposed to reversible deactivation radical polymerization, the living polymerization is demonstrated to be viable to high monomer conversion and through multiple monomer addition steps. Successful preparation of a multiblock copolypeptoid is proof for a highly living and robust character of the solid-phase peptoid polymerization. }, added-at = {2014-03-18T13:58:10.000+0100}, author = {Gangloff, Niklas and Fetsch, Corinna and Luxenhofer, Robert}, biburl = {https://www.bibsonomy.org/bibtex/2cf760fcc9149fd542fffefefeabd1a69/lctm}, doi = {10.1002/marc.201300269}, interhash = {12e280ebc7028714a45dedfa334dad78}, intrahash = {cf760fcc9149fd542fffefefeabd1a69}, issn = {1521-3927}, journal = {Macromolecular Rapid Communications}, keywords = {living opening polymerization polypeptoids ring rluxenhofer}, number = 12, pages = {997--1001}, publisher = {WILEY-VCH Verlag}, timestamp = {2014-03-18T13:58:10.000+0100}, title = {Polypeptoids by Living Ring-Opening Polymerization of N-Substituted N-Carboxyanhydrides from Solid Supports}, url = {http://dx.doi.org/10.1002/marc.201300269}, volume = 34, year = 2013 }