Article,

High-pressure Raman study of taurine crystal

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JOURNAL OF RAMAN SPECTROSCOPY, 32 (1): 27-32 (2001)
DOI: 10.1002/1097-4555(200101)32:1<27::AID-JRS662>3.0.CO;2-H

Abstract

Single-crystal samples of taurine, NH3C2H4SO3, were studied by Raman spectroscopy in a diamond-anvil cell up to pressures of 5.6 GPa. From the analysis of the results we observed that the crystal undergoes a phase transition at about 0.7 GPa. The transition is accompanied by the appearance of a phonon in the external mode region of the spectrum and by changes of both the wavenumber of the CCN bending and of the CSH torsional vibrations. Additionally evidence for a second phase transition occurring at 5.2 GPa was observed. Pressure coefficients for all modes observed in this work are also given. Copyright (C) 2001 John Wiley & Sons, Ltd.

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