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Attraction between equally charged surfaces mediated by nanoparticles

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Abstract Book of the XXIII IUPAP International Conference on Statistical Physics, Genova, Italy, (9-13 July 2007)

Abstract

The interaction between equal, uniformly charged flat surfaces, separated by a solution of spheroidal or rod-like nanoparticles was studied theoretically and experimentally. In the theory the nanoparticles were assumed to have a spatially distributed electric charge. The density functional theory for the nanoparticles within the solution was developed. The excluded volume effect was taken into account by the closest approach of the nanoparticles to the charged surfaces. It was shown that for large enough dimensions of nanoparticles and large enough surface charge densities of membrane surfaces, the two equally charged surfaces could experience an attractive force due to the spatially distributed charges within the nanoparticles.

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