Evaluation of CO2 sequestration in formation brine or in seawater needs highly accurate experimental data or models of pressure-volume-temperature-composition (PVTx) properties for the CO2-H2O and CO2-H2O-NaCl systems. This paper presents a comprehensive review of the experimental PVTx properties and the thermodynamic models of these two systems.
The following conclusions are drawn from the review:
(1) About two-thirds of experimental data are consistent with each other, where the uncertainty in liquid volumes is within 0.5\%, and that in gas volumes within 2\%. However, this accuracy is not sufficient for assessing CO2 sequestration. Amo…(more)
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%0 Journal Article
%1 Hu2007
%A Hu, Jiawen
%A Duan, Zhenhao
%A Zhu, Chen
%A Chou, I-Ming
%D 2007
%J Chemical Geology
%K 2007 CO2 NaCl density overview water
%N 3-4
%P 249 - 267
%R 10.1016/j.chemgeo.2006.11.011
%T PVTx properties of the CO2-H2O and CO2-H2O-NaCl systems below 647 K: Assessment of experimental data and thermodynamic models
%U http://dx.doi.org/10.1016/j.chemgeo.2006.11.011
%V 238
%X Evaluation of CO2 sequestration in formation brine or in seawater needs highly accurate experimental data or models of pressure-volume-temperature-composition (PVTx) properties for the CO2-H2O and CO2-H2O-NaCl systems. This paper presents a comprehensive review of the experimental PVTx properties and the thermodynamic models of these two systems.
The following conclusions are drawn from the review:
(1) About two-thirds of experimental data are consistent with each other, where the uncertainty in liquid volumes is within 0.5\%, and that in gas volumes within 2\%. However, this accuracy is not sufficient for assessing CO2 sequestration. Among the data sets for liquids, only a few are available for accurate modeling of CO2 sequestration. These data have an error of about 0.1\% on average, roughly covering from 273 to 642 K and from 1 to 35 MPa;
(2) There is a shortage of volumetric data of saturated vapor phase.
(3) There are only a few data sets for the ternary liquids, and they are inconsistent with each other, where only a couple of data sets can be used to test a predictive density model for CO2 sequestration;
(4) Although there are a few models with accuracy close to that of experiments, none of them is accurate enough for CO2 sequestration modeling, which normally needs an accuracy of density better than 0.1\%. Some calculations are made available on www.geochem-model.org.
@article{Hu2007,
abstract = {Evaluation of CO2 sequestration in formation brine or in seawater needs highly accurate experimental data or models of pressure-volume-temperature-composition (PVTx) properties for the CO2-H2O and CO2-H2O-NaCl systems. This paper presents a comprehensive review of the experimental PVTx properties and the thermodynamic models of these two systems.
The following conclusions are drawn from the review:
(1) About two-thirds of experimental data are consistent with each other, where the uncertainty in liquid volumes is within 0.5\%, and that in gas volumes within 2\%. However, this accuracy is not sufficient for assessing CO2 sequestration. Among the data sets for liquids, only a few are available for accurate modeling of CO2 sequestration. These data have an error of about 0.1\% on average, roughly covering from 273 to 642 K and from 1 to 35 MPa;
(2) There is a shortage of volumetric data of saturated vapor phase.
(3) There are only a few data sets for the ternary liquids, and they are inconsistent with each other, where only a couple of data sets can be used to test a predictive density model for CO2 sequestration;
(4) Although there are a few models with accuracy close to that of experiments, none of them is accurate enough for CO2 sequestration modeling, which normally needs an accuracy of density better than 0.1\%. Some calculations are made available on www.geochem-model.org.},
added-at = {2011-01-19T18:06:23.000+0100},
author = {Hu, Jiawen and Duan, Zhenhao and Zhu, Chen and Chou, I-Ming},
biburl = {https://www.bibsonomy.org/bibtex/21277c08eb402839392d6d96ad12c38dc/thorade},
description = {ScienceDirect - Chemical Geology : PVTx properties of the CO2–H2O and CO2–H2O–NaCl systems below 647 K: Assessment of experimental data and thermodynamic models},
doi = {10.1016/j.chemgeo.2006.11.011},
interhash = {7774e04d9c811f19535166ff18d8d7c0},
intrahash = {1277c08eb402839392d6d96ad12c38dc},
issn = {0009-2541},
journal = {Chemical Geology},
keywords = {2007 CO2 NaCl density overview water},
number = {3-4},
pages = {249 - 267},
timestamp = {2011-07-21T11:08:15.000+0200},
title = {PVTx properties of the CO2-H2O and CO2-H2O-NaCl systems below 647 K: Assessment of experimental data and thermodynamic models},
url = {http://dx.doi.org/10.1016/j.chemgeo.2006.11.011},
volume = 238,
year = 2007
}