Article,

PVTx properties of the CO2-H2O and CO2-H2O-NaCl systems below 647 K: Assessment of experimental data and thermodynamic models

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Chemical Geology, 238 (3-4): 249 - 267 (2007)
DOI: 10.1016/j.chemgeo.2006.11.011

Abstract

Evaluation of CO2 sequestration in formation brine or in seawater needs highly accurate experimental data or models of pressure-volume-temperature-composition (PVTx) properties for the CO2-H2O and CO2-H2O-NaCl systems. This paper presents a comprehensive review of the experimental PVTx properties and the thermodynamic models of these two systems. The following conclusions are drawn from the review: (1) About two-thirds of experimental data are consistent with each other, where the uncertainty in liquid volumes is within 0.5\%, and that in gas volumes within 2\%. However, this accuracy is not sufficient for assessing CO2 sequestration. Amo…(more)

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