%0 Journal Article %1 RN203 %A Barahona, P. %A Galdamez, A. %A Lopez-Vergara, F. %A Manriquez, V. %A Pena, O. %D 2014 %I 2014 Elsevier Inc. %J Journal of Solid State Chemistry %K chalcospinel, copper crystal cucr2se4, cuti2s4, dqcauchile electrical-properties, geometry, lithium, magnetic polyhedra, properties, spinel structure, thiospinels, transport-properties, %P 114-120 %R 10.1016/j.jssc.2014.01.017 %T Crystal Structure and Magnetic Properties of Titanium-Based Cuti2-Xmxs4 and Cucr2-Xtixse4 Chalcospinels %U /brokenurl#<Go to ISI>://WOS:000333071400017 %V 212 %X CuTi2-xMxS4 (M=Fe, Mn, Co; x=0.3, 0.5) and CuCr2-xTixSe4 (x=03, 0.5, 0.7) chalcospinels were synthesized by conventional solid-state reactions. Their crystal structures were determined by single-crystal X-ray diffraction. All of the phases crystallized in cubic spinel-type structures (space group, Fd (3) over barm). For all of the chalcospinel compounds, the edge-length distortion parameter (ELD) indicated that the most distorted polyhedron was Q(Ti,M)(3)Cu, which displayed an similar to 8% distortion from an ideal tetrahedron structure (Q=S or Se)., The Mn-based thiospinel CuMn0.3Ti1.7S4 is paramagnetic, whereas the Fe-based thiospinels (CuTi2-xFexS4; x=0.3 and 0.7) are strongly antiferromagnetic due to their spin-glass states. The magnetic susceptibility measurements indicated ferromagnetic behavior for the selenospinels (CuCr2-xTixSe4; x=0.3, 0.5 and 0.7).

@article{RN203, abstract = {CuTi2-xMxS4 (M=Fe, Mn, Co; x=0.3, 0.5) and CuCr2-xTixSe4 (x=03, 0.5, 0.7) chalcospinels were synthesized by conventional solid-state reactions. Their crystal structures were determined by single-crystal X-ray diffraction. All of the phases crystallized in cubic spinel-type structures (space group, Fd (3) over barm). For all of the chalcospinel compounds, the edge-length distortion parameter (ELD) indicated that the most distorted polyhedron was Q[(Ti,M)(3)Cu], which displayed an similar to 8% distortion from an ideal tetrahedron structure (Q=S or Se)., The Mn-based thiospinel CuMn0.3Ti1.7S4 is paramagnetic, whereas the Fe-based thiospinels (CuTi2-xFexS4; x=0.3 and 0.7) are strongly antiferromagnetic due to their spin-glass states. The magnetic susceptibility measurements indicated ferromagnetic behavior for the selenospinels (CuCr2-xTixSe4; x=0.3, 0.5 and 0.7). }, added-at = {2019-12-04T03:57:35.000+0100}, author = {Barahona, P. and Galdamez, A. and Lopez-Vergara, F. and Manriquez, V. and Pena, O.}, biburl = {https://www.bibsonomy.org/bibtex/29a5781276dcabf040685a8fbfa4f811f/dqcauchile}, doi = {10.1016/j.jssc.2014.01.017}, interhash = {8ba3d7da8f3c5e27f4112b7ea5a27805}, intrahash = {9a5781276dcabf040685a8fbfa4f811f}, issn = {0022-4596}, journal = {Journal of Solid State Chemistry}, keywords = {chalcospinel, copper crystal cucr2se4, cuti2s4, dqcauchile electrical-properties, geometry, lithium, magnetic polyhedra, properties, spinel structure, thiospinels, transport-properties,}, pages = {114-120}, publisher = {2014 Elsevier Inc.}, timestamp = {2019-12-04T03:58:17.000+0100}, title = {Crystal Structure and Magnetic Properties of Titanium-Based Cuti2-Xmxs4 and Cucr2-Xtixse4 Chalcospinels}, type = {Journal Article}, url = {/brokenurl#<Go to ISI>://WOS:000333071400017}, volume = 212, year = 2014 }