%0 Journal Article %1 ISI:000308827100065 %A Notash, Behrouz %A Safari, Nasser %A Khavasi, Hamid Reza %C THOMAS GRAHAM HOUSE, SCIENCE PARK, MILTON RD, CAMBRIDGE CB4 0WF, CAMBS, ENGLAND %D 2012 %I ROYAL SOC CHEMISTRY %J CRYSTENGCOMM %K imported %N 20 %P 6788-6796 %R 10.1039/c2ce25554e %T Anion-controlled structural motif in one-dimensional coordination networks via cooperative weak noncovalent interactions %V 14 %X The self-assembly of an exoditopic N-donor ligand (3-py-3-py) with HgX2 (X = Cl, Br, I) was investigated. X-ray structure analysis shows that all the compounds have an infinite one-dimensional structure and the Hg(II) ions are in a distorted trigonal pyramidal N2HgX2 geometry. Our results indicate that the coordinated anion can control the structural motif of the resulting one-dimensional coordination polymers through cooperative weak noncovalent interactions. In the case of Hg-2(mu-3-py-3-py)(2)Cl-4(n) (1) and Hg-2(mu-3-py-3-py)(2)Br-4(n) (2), the 1D zigzag chains are constructed as a consequence of cooperative noncovalent interactions, such as hydrogen bonds, halogen center dot center dot center dot pi and pi-pi interactions. However, for Hg(mu-3-py-3-py)I-2(n) (3), the coordinated iodide ion tunes the folding of the 1D structure into a helical array by bifurcated C-H center dot center dot center dot I-Hg hydrogen bonds and pi-pi interactions in a cooperative manner.

@article{ISI:000308827100065, abstract = {{The self-assembly of an exoditopic N-donor ligand (3-py-3-py) with HgX2 (X = Cl, Br, I) was investigated. X-ray structure analysis shows that all the compounds have an infinite one-dimensional structure and the Hg(II) ions are in a distorted trigonal pyramidal N2HgX2 geometry. Our results indicate that the coordinated anion can control the structural motif of the resulting one-dimensional coordination polymers through cooperative weak noncovalent interactions. In the case of {[}Hg-2(mu-3-py-3-py)(2)Cl-4](n) (1) and {[}Hg-2(mu-3-py-3-py)(2)Br-4](n) (2), the 1D zigzag chains are constructed as a consequence of cooperative noncovalent interactions, such as hydrogen bonds, halogen center dot center dot center dot pi and pi-pi interactions. However, for {[}Hg(mu-3-py-3-py)I-2](n) (3), the coordinated iodide ion tunes the folding of the 1D structure into a helical array by bifurcated C-H center dot center dot center dot I-Hg hydrogen bonds and pi-pi interactions in a cooperative manner.}}, added-at = {2017-05-10T15:29:29.000+0200}, address = {{THOMAS GRAHAM HOUSE, SCIENCE PARK, MILTON RD, CAMBRIDGE CB4 0WF, CAMBS, ENGLAND}}, affiliation = {{Safari, N (Reprint Author), Shahid Beheshti Univ, Dept Chem, GC, Tehran 1983963113, Iran. Notash, Behrouz; Safari, Nasser; Khavasi, Hamid Reza, Shahid Beheshti Univ, Dept Chem, GC, Tehran 1983963113, Iran.}}, author = {Notash, Behrouz and Safari, Nasser and Khavasi, Hamid Reza}, author-email = {{n-safari@sbu.ac.ir}}, biburl = {https://www.bibsonomy.org/bibtex/23920efd9e04b1c32f063ba846de25bb9/hkhavasi}, cited-references = {{Aakeroy CB, 2010, CRYSTENGCOMM, V12, P22, DOI 10.1039/b919819a. Agou T, 2011, INORG CHEM, V50, P3183, DOI 10.1021/ic200268c. 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Zheng XD, 2010, CRYSTENGCOMM, V12, P324, DOI 10.1039/b911991d. Zhou HP, 2009, CRYST GROWTH DES, V9, P3789, DOI 10.1021/cg900520j. Zhu X, 2009, CRYSTENGCOMM, V11, P997, DOI 10.1039/b901780c. {[}Anonymous], 1995, INT TABLES XRAY CRYS, VC.}}, doc-delivery-number = {{006NY}}, doi = {{10.1039/c2ce25554e}}, funding-acknowledgement = {{Graduate Study Councils of Shahid Beheshti University, G. C.}}, funding-text = {{We thank the Graduate Study Councils of Shahid Beheshti University, G. C. for financial support.}}, interhash = {8e8ed3a7464fff1885c83fe81da65c2f}, intrahash = {3920efd9e04b1c32f063ba846de25bb9}, issn = {{1466-8033}}, journal = {{CRYSTENGCOMM}}, journal-iso = {{Crystengcomm}}, keywords = {imported}, keywords-plus = {{PI-PI INTERACTIONS; HYDROGEN-BONDING INTERACTIONS; METAL-ORGANIC FRAMEWORKS; ZIGZAG CHAINS; SOLID-STATE; AROMATIC INTERACTIONS; STACKING INTERACTIONS; SILVER(I) COMPLEXES; TOPOLOGICAL CONTROL; CONTAINING LIGANDS}}, language = {{English}}, number = {{20}}, number-of-cited-references = {{141}}, pages = {{6788-6796}}, publisher = {{ROYAL SOC CHEMISTRY}}, research-areas = {{Chemistry; Crystallography}}, times-cited = {{22}}, timestamp = {2017-05-10T15:29:29.000+0200}, title = {{Anion-controlled structural motif in one-dimensional coordination networks via cooperative weak noncovalent interactions}}, type = {{Article}}, unique-id = {{ISI:000308827100065}}, usage-count-last-180-days = {{1}}, usage-count-since-2013 = {{25}}, volume = {{14}}, web-of-science-categories = {{Chemistry, Multidisciplinary; Crystallography}}, year = {{2012}} }