Artikel,

Oxygen stoichiometry in Sr3Mn2O7-delta: A Raman scattering investigation

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PHYSICAL REVIEW B, 62 (21): 13809-13811 (2000)
DOI: 10.1103/PhysRevB.62.13809

Zusammenfassung

Polycrystalline Sr3Mn2O6.5 and Sr3Mn2O7 layered manganites were studied at room temperature using Raman spectroscopy. While the phonon spectrum of the stoichiometric Sr3Mn2O7 sample is consistent with the group theoretical analysis for the 14/mmm structure, additional features are observed in the phonon spectrum of the oxygen deficient Sr3Mn2O6.5 sample. Based on an analysis of the temperature dependence of the Raman spectrum of Sr3Mn2O6.5 and a comparison with the Raman spectrum of La0.4Sr2.6Mn2O7-delta (delta= 0.0 and 0.35), we conclude that the `extra' modes should be viewed as disorder induced Raman scattering.

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