%0 Journal Article %1 Frost:1990p1683 %A Frost, Michael %A Smith, Ian %A Smith, Ian %D 1990 %J Journal of the Chemical Society, Faraday Transactions %K imported %N 10 %P 1751--6 %T Rate constants for the reactions of methoxy and ethoxy radicals with nitrogen dioxide over a range of temperatures and total pressures %U http://www.google.com/search?client=safari&rls=en-us&q=Rate+constants+for+the+reactions+of+methoxy+and+ethoxy+radicals+with+nitrogen+dioxide+over+a+range+of+temperatures+and+total+pressures&ie=UTF-8&oe=UTF-8 %V 86 %X The kinetics of the title reactions have been studied using pulsed laser photolysis to create the radicals from the corresponding alkyl nitrite and by time-resolved, laser-induced fluorescence to observe the decay of the radical concn. At 295 K, rate consts. for CH3O + NO2 have been measured in the presence of Ar (6-100 Torr), He (30-100 Torr) and CF4 (30-125 Torr). The assocn. reaction to CH3ONO2 appears to predominate, and rate consts. in the limit of low and high pressures are deduced. A limited no. of measurements is also reported for this reaction at 390 K. The rate of the reaction of C2H5O with NO2 at 295 K is the same in the presence of 15 and 100 Torr of Ar, and the measurements yield a rate const.: (k.../10-11 cm3 mol.-1 s-1) = 2.8 +- 0.3. %Z Copyright 2003 ACS CAPLUS AN 1990:458424 CAN 113:58424 22-13 Physical Organic Chemistry Sch. Chem.,Univ. Birmingham,Birmingham,UK. JCFTEV 0956-5000 written in English. Kinetics (of nitrogen dioxide with ethoxy and methoxy radicals)

@article{Frost:1990p1683, abstract = {The kinetics of the title reactions have been studied using pulsed laser photolysis to create the radicals from the corresponding alkyl nitrite and by time-resolved, laser-induced fluorescence to observe the decay of the radical concn. At 295 K, rate consts. for CH3O + NO2 have been measured in the presence of Ar (6-100 Torr), He (30-100 Torr) and CF4 (30-125 Torr). The assocn. reaction to CH3ONO2 appears to predominate, and rate consts. in the limit of low and high pressures are deduced. A limited no. of measurements is also reported for this reaction at 390 K. The rate of the reaction of C2H5O with NO2 at 295 K is the same in the presence of 15 and 100 Torr of Ar, and the measurements yield a rate const.: (k.../10-11 cm3 mol.-1 s-1) = 2.8 +- 0.3.}, added-at = {2010-06-22T19:38:37.000+0200}, annote = {Copyright 2003 ACS CAPLUS AN 1990:458424 CAN 113:58424 22-13 Physical Organic Chemistry Sch. Chem.,Univ. Birmingham,Birmingham,UK. JCFTEV 0956-5000 written in English. Kinetics (of nitrogen dioxide with ethoxy and methoxy radicals)}, author = {Frost, Michael and Smith, Ian and Smith, Ian}, biburl = {https://www.bibsonomy.org/bibtex/259db3efd07aa26e6929e7bd4ede4b85e/gsmith}, date-added = {2010-03-10 16:47:20 -0500}, date-modified = {2010-04-28 14:52:59 -0400}, interhash = {acdc484b7e1a2c1dcc905a2e29a552f8}, intrahash = {59db3efd07aa26e6929e7bd4ede4b85e}, journal = {Journal of the Chemical Society, Faraday Transactions}, keywords = {imported}, label = {rec-number 306}, number = 10, pages = {1751--6}, rating = {0}, timestamp = {2010-06-22T19:38:59.000+0200}, title = {Rate constants for the reactions of methoxy and ethoxy radicals with nitrogen dioxide over a range of temperatures and total pressures}, uri = {papers://E88B624E-D406-46FF-9D95-BB9C1AAE3FDC/Paper/p1683}, url = {http://www.google.com/search?client=safari&rls=en-us&q=Rate+constants+for+the+reactions+of+methoxy+and+ethoxy+radicals+with+nitrogen+dioxide+over+a+range+of+temperatures+and+total+pressures&ie=UTF-8&oe=UTF-8}, volume = 86, year = 1990 }