%0 Journal Article %1 ji2018copolymer %A Ji, Deyang %A Li, Tao %A Zou, Ye %A Chu, Ming %A Zhou, Ke %A Liu, Jinyu %A Tian, Guofeng %A Zhang, Zhaoyang %A Zhang, Xu %A Li, Liqiang %A Wu, Dezhen %A Dong, Huanli %A Miao, Qian %A Fuchs, Harald %A Hu, Wenping %D 2018 %J Nature Communications %K OFET copolymers dielectrics new_material organic %N 1 %P 2339-- %R 10.1038/s41467-018-04665-z %T Copolymer dielectrics with balanced chain-packing density and surface polarity for high-performance flexible organic electronics %U https://doi.org/10.1038/s41467-018-04665-z %V 9 %X The ever-increasing demand for flexible electronics calls for the development of low-voltage and high-mobility organic thin-film transistors (OTFTs) that can be integrated into emerging display and labeling technologies. Polymer dielectrics with comprehensive and balanced dielectric properties (i.e., a good balance between their insulating characteristics and compatibility with organic semiconductors) are considered particularly important for this end. Here, we introduce a simple but highly efficient strategy to realize this target by using a new type of copolymer as dielectrics. Benefiting from both high chain packing density guaranteeing dielectric properties and surface polarity optimizing molecular packing of organic semiconductors, this rationally designed copolymer dielectric endows flexible OTFTs with high mobility (5.6 cm2 V−1 s−1), low operating voltage (3 V) and outstanding stability. Further, their applicability in integrated circuits is verified. The excellent device performance shows exciting prospects of this molecular-scale engineered copolymer for the realization of plastic high-performance integrated electronics.

@article{ji2018copolymer, abstract = {The ever-increasing demand for flexible electronics calls for the development of low-voltage and high-mobility organic thin-film transistors (OTFTs) that can be integrated into emerging display and labeling technologies. Polymer dielectrics with comprehensive and balanced dielectric properties (i.e., a good balance between their insulating characteristics and compatibility with organic semiconductors) are considered particularly important for this end. Here, we introduce a simple but highly efficient strategy to realize this target by using a new type of copolymer as dielectrics. Benefiting from both high chain packing density guaranteeing dielectric properties and surface polarity optimizing molecular packing of organic semiconductors, this rationally designed copolymer dielectric endows flexible OTFTs with high mobility (5.6 cm2 V−1 s−1), low operating voltage (3 V) and outstanding stability. Further, their applicability in integrated circuits is verified. The excellent device performance shows exciting prospects of this molecular-scale engineered copolymer for the realization of plastic high-performance integrated electronics.}, added-at = {2018-07-16T11:12:47.000+0200}, author = {Ji, Deyang and Li, Tao and Zou, Ye and Chu, Ming and Zhou, Ke and Liu, Jinyu and Tian, Guofeng and Zhang, Zhaoyang and Zhang, Xu and Li, Liqiang and Wu, Dezhen and Dong, Huanli and Miao, Qian and Fuchs, Harald and Hu, Wenping}, biburl = {https://www.bibsonomy.org/bibtex/202c4c55e9b7ddb3f021bc08e2c590289/bretschneider_m}, doi = {10.1038/s41467-018-04665-z}, interhash = {adc72d4f36bb24e72086009633a37dab}, intrahash = {02c4c55e9b7ddb3f021bc08e2c590289}, issn = {20411723}, journal = {Nature Communications}, keywords = {OFET copolymers dielectrics new_material organic}, number = 1, pages = {2339--}, refid = {Ji2018}, timestamp = {2018-07-16T11:12:47.000+0200}, title = {Copolymer dielectrics with balanced chain-packing density and surface polarity for high-performance flexible organic electronics}, url = {https://doi.org/10.1038/s41467-018-04665-z}, volume = 9, year = 2018 }