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A framework for surface enhanced circular dichroism spectroscopy mediated by non-chiral nanoantennas

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(2012)cite arxiv:1209.0288 Comment: 12 pages, 2 figures.

Abstract

We investigate light matter interactions for chiral molecules in the presence of non-chiral nanoantennas. Isotropic nanostructures supporting optical-frequency electric or magnetic dipoles are sufficient to locally enhance the excitation of a molecule's chiral polarizability and thus its circular dichroism spectrum. However, simultaneous electric and magnetic dipoles are necessary to achieve a net, spatially-averaged enhancement. Our contribution provides a theoretical framework to understand chiral light-matter interactions at the nanoscale and sets the necessary and sufficient conditions to enhance circular dichroism spectroscopy in the presence of nanoantennas. The results may lead to new, field-enhanced, chiral spectroscopic techniques.

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