Аннотация
The universal diagram of states of hydrophobically modified polyelectrolytes
in dilute salt-free solutions is calculated in the framework of the
scaling approach. The equilibrium conformations of these polymers
were classified using two parameters-geometric and energetic ratios
of hydrophobic and polyelectrolyte blocks in unassociated states
(the ratio of block sizes and the ratio of block energies). The hydrophobically
modified polyelectrolytes self-organize either into necklaces of
hairy, crew-cut, or braided micelles or into wormlike cylindrical
micelles depending on the values of these two parameters. The universal
diagram of states is modified by the counterion condensation.
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