Article,

catena-poly(5,5 `-dimethyl-2,2 `-bipyridine-kappa N-2,N `)cadmium(II)-di-mu-chlorido

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ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 64 (10): M1233-U184 (October 2008)
DOI: {10.1107/S1600536808027657}

Abstract

The asymmetric unit of the title compound, CdCl2-(C12H12N2)(n), contains one half-molecule; a twofold rotation axis passes through the Cd atom. The Cd-II atom is six-coordinated in a distorted octahedral configuration by two N atoms from 2,2'-bipyridine-5,5'-dimethyl and four bridging Cl atoms. The bridging function of the chloro atoms leads to a one-dimensional chain structure. There is a pi-pi contact between the pyridine rings centroid-centroid distance = 3.9807 (9) (A) over circle.

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