Article,

Born–Oppenheimer and non-Born–Oppenheimer contributions to time-dependent electron momenta

, and .
J. Chem. Phys., 152 (20): 204310 (May 2020)
DOI: 10.1063/5.0004560

Abstract

Using a model system for a coupled electron–nuclear motion, we calculate time-dependent expectation values of the electronic momentum operator. Whereas, within the velocity form, this quantity vani...

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