%0 Journal Article %1 ISI:000292838900025 %A Mohammadnezhad, Gholamhossein %A Amini, Mostafa M. %A Khavasi, Hamid Reza %C 233 SPRING ST, NEW YORK, NY 10013 USA %D 2011 %I SPRINGER/PLENUM PUBLISHERS %J JOURNAL OF CHEMICAL CRYSTALLOGRAPHY %K Crystal Magnesium; bridged} mu-Oxo structure; {Alkoxide; %N 8 %P 1224-1227 %R 10.1007/s10870-011-0077-8 %T Synthesis and Crystal Structure of Bis(mu(3)-4-Oxapentan-2-onato)-Tetrakis(mu(2)-4-Oxapentan-2-onato)-Tetra -Magnesium Dichloride Dichloromethane %V 41 %X A new magnesium alkoxide which posses centrosymmetric tetranuclear structure derived from 1-methoxy-2-propanol, a functionalized alcohol containing asymmetric carbon. X-ray analysis of single crystal shows an open dicubane-like structure with triple-bridging alkoxo groups between alternating five- and six-coordinated magnesium atoms. There are six alkoxo bridging groups in which two of them bridge three metal centers and the other four bridge two. All of the etheric-oxygens are coordinated to magnesium and provide a rigid structure. Two chlorine atoms are bonded to five-coordinated magnesium. This compound crystallizes in the monoclinic system with a = 10.040(6) C-0, b = 14.004(9) C-0, c = 15.344(5) C-0, beta = 95.55(9)Ee, Z = 2 and V = 2147 C-03 in the space group of P2(1)/n.

@article{ISI:000292838900025, abstract = {{A new magnesium alkoxide which posses centrosymmetric tetranuclear structure derived from 1-methoxy-2-propanol, a functionalized alcohol containing asymmetric carbon. X-ray analysis of single crystal shows an open dicubane-like structure with triple-bridging alkoxo groups between alternating five- and six-coordinated magnesium atoms. There are six alkoxo bridging groups in which two of them bridge three metal centers and the other four bridge two. All of the etheric-oxygens are coordinated to magnesium and provide a rigid structure. Two chlorine atoms are bonded to five-coordinated magnesium. This compound crystallizes in the monoclinic system with a = 10.040(6) C-0, b = 14.004(9) C-0, c = 15.344(5) C-0, beta = 95.55(9)Ee, Z = 2 and V = 2147 C-03 in the space group of P2(1)/n.}}, added-at = {2017-05-10T15:29:29.000+0200}, address = {{233 SPRING ST, NEW YORK, NY 10013 USA}}, affiliation = {{Amini, MM (Reprint Author), Shahid Beheshti Univ Med Sci, Dept Chem, GC Evin, Tehran 1983963113, Iran. Mohammadnezhad, Gholamhossein; Amini, Mostafa M.; Khavasi, Hamid Reza, Shahid Beheshti Univ Med Sci, Dept Chem, GC Evin, Tehran 1983963113, Iran.}}, author = {Mohammadnezhad, Gholamhossein and Amini, Mostafa M. and Khavasi, Hamid Reza}, author-email = {{m-pouramini@cc.sbu.ac.ir}}, biburl = {https://www.bibsonomy.org/bibtex/210661c06a25ab76a13d20dfd816708a2/hkhavasi}, cited-references = {{Albaric L, 1997, POLYHEDRON, V16, P587, DOI 10.1016/0277-5387(96)00327-0. Amini MM, 2007, MATER RES BULL, V42, P563, DOI 10.1016/j.materresbull.2006.06.011. Boyle TJ, 2000, INORG CHEM, V39, P5133, DOI 10.1021/ic000432a. Dimitrov A, 2008, ANGEW CHEM INT EDIT, V47, P190, DOI 10.1002/anie.200703516. Lichtenberger R, 2010, J MATER CHEM, V20, P9287, DOI 10.1039/c0jm00993h. Linnert M, 2008, POLYHEDRON, V27, P151, DOI 10.1016/j.poly.2007.08.039. Mathur S, 2004, CHEM MATER, V16, P1304, DOI 10.1021/cm0311675. Mishra S, 2010, INORG CHEM, V49, P11184, DOI 10.1021/ic102134w. Mohammadnezhad G, 2010, DALTON T, V39, P10830, DOI 10.1039/c0dt00983k. Moniz SJA, 2010, J MATER CHEM, V20, P7881, DOI 10.1039/c0jm01720e. SATTARZADEH E, 2011, MATER LETT, V66, P527. SCHUBERT U, 1995, CHEM MATER, V7, P2010, DOI 10.1021/cm00059a007. Sheldrick G.M., 1997, SHELX97 PROGRAM CRYS. Sobota P, 1996, CHEM COMMUN, P1923, DOI 10.1039/cc9960001923. Stoe Cie, 2005, X RED VERS 1 28B PRO. Stoe \& Cie, 2004, X SHAPE VERS 2 05 PR. Stoe \& Cie, 2005, X AREA VERS 1 30 PRO. Stoe \& Cie, 2000, X STEP32 VERS 1 07B. THOMS H, 1995, J MATER CHEM, V5, P589, DOI 10.1039/jm9950500589. Veith M, 2011, DALTON T, V40, P1175, DOI 10.1039/c0dt00830c. Walfort B, 2004, ACTA CRYSTALLOGR C, V60, pM482, DOI 10.1107/S010827010401933X. WANG F, 2009, J ALLOY COMPD, V86, P521. Wang XL, 2011, COLLOID POLYM SCI, V289, P423, DOI 10.1007/s00396-010-2372-x. Yang XY, 2011, CHEM COMMUN, V47, P2763, DOI 10.1039/c0cc03734f. Zechmann CA, 2001, INORG CHIM ACTA, V319, P137, DOI 10.1016/S0020-1693(01)00447-9.}}, doc-delivery-number = {{793QT}}, doi = {{10.1007/s10870-011-0077-8}}, funding-acknowledgement = {{Shahid Beheshti University}}, funding-text = {{The authors thank Shahid Beheshti University for financial support.}}, interhash = {ea61390cbd20d6aa361d59a740a5ffe1}, intrahash = {10661c06a25ab76a13d20dfd816708a2}, issn = {{1074-1542}}, journal = {{JOURNAL OF CHEMICAL CRYSTALLOGRAPHY}}, journal-iso = {{J. Chem. Crystallogr.}}, keywords = {Crystal Magnesium; bridged} mu-Oxo structure; {Alkoxide;}, keywords-plus = {{MAGNESIUM ALKOXIDE; PRECURSORS; COMPLEXES; CHEMISTRY; MGAL2O4; METAL}}, language = {{English}}, month = {{AUG}}, number = {{8}}, number-of-cited-references = {{25}}, pages = {{1224-1227}}, publisher = {{SPRINGER/PLENUM PUBLISHERS}}, research-areas = {{Crystallography; Spectroscopy}}, researcherid-numbers = {{G, Neela/H-3016-2014 Mohammadnezhad, Gholamhossein/F-8582-2017}}, times-cited = {{1}}, timestamp = {2017-05-10T15:29:29.000+0200}, title = {{Synthesis and Crystal Structure of Bis(mu(3)-4-Oxapentan-2-onato)-Tetrakis(mu(2)-4-Oxapentan-2-onato)-Tetra -Magnesium Dichloride Dichloromethane}}, type = {{Article}}, unique-id = {{ISI:000292838900025}}, usage-count-last-180-days = {{0}}, usage-count-since-2013 = {{5}}, volume = {{41}}, web-of-science-categories = {{Crystallography; Spectroscopy}}, year = {{2011}} }