%0 Journal Article %1 ISI:000280283400011 %A Alizadeh, Robabeh %A Amani, Vahid %A Farshady, Ali Akbar %A Khavasi, Hamid Reza %C 4 PARK SQUARE, MILTON PARK, ABINGDON OX14 4RN, OXON, ENGLAND %D 2010 %I TAYLOR & FRANCIS LTD %J JOURNAL OF COORDINATION CHEMISTRY %K 10-phenanthroline; 2'-bipyridine; 4; 5'-dimethyl-2; 5; 7-diphenyl-1; Crystal structure} {Mercury(II); %N 12 %P 2122-2131 %R 10.1080/00958972.2010.496128 %T Synthesis, characterization, and crystal structure determination of two mercury(II) dimer complexes with 4,7-diphenyl-1,10-phenanthroline, 5,5'-dimethyl-2,2'-bipyridine and bromide %V 63 %X Mercury(II) complexes, \Hg(Ph2phen)(-Br)2Br2\ center dot CH3CN (1) and \Hg(dmbpy)(mu-Br)2Br2\(2) (where Ph2phen is 4,7-diphenyl-1,10-phenanthroline and dmbpy is 5,5'-dimethyl-2,2'-bipyridine), were synthesized from reaction of HgBr2 with Ph2phen and dmbpy in CH3CN and CH3OH. Both complexes were thoroughly characterized by elemental analysis, infrared, 1H and 13C NMR spectroscopy and single-crystal X-ray diffraction. Complexes 1 and 2 crystallize in the space group P21/n of the monoclinic and P1 of the triclinic systems and contain four and one molecules per unit cell, respectively. The unit cell dimensions for 1 are: a = 20.422(4) angstrom, b = 11.384(2) angstrom, c = 20.665(4) angstrom, and = 109.94(3)degrees and for 2 are: a = 8.7470(17) angstrom, b = 8.8328(18) angstrom, c = 9.4950(19) angstrom and = 75.47(3)degrees, = 82.21(3)degrees, = 85.56(3)degrees. According to X-ray structure determination both complexes are five coordinate with three bromides and one bidentate ligand; one bromide is set at a semi-bridging position.

@article{ISI:000280283400011, abstract = {{Mercury(II) complexes, \{{[}Hg(Ph2phen)(-Br)]2Br2\} center dot CH3CN (1) and \{{[}Hg(dmbpy)(mu-Br)]2Br2\}(2) (where Ph2phen is 4,7-diphenyl-1,10-phenanthroline and dmbpy is 5,5'-dimethyl-2,2'-bipyridine), were synthesized from reaction of HgBr2 with Ph2phen and dmbpy in CH3CN and CH3OH. Both complexes were thoroughly characterized by elemental analysis, infrared, 1H and 13C NMR spectroscopy and single-crystal X-ray diffraction. Complexes 1 and 2 crystallize in the space group P21/n of the monoclinic and P1 of the triclinic systems and contain four and one molecules per unit cell, respectively. The unit cell dimensions for 1 are: a = 20.422(4) angstrom, b = 11.384(2) angstrom, c = 20.665(4) angstrom, and = 109.94(3)degrees and for 2 are: a = 8.7470(17) angstrom, b = 8.8328(18) angstrom, c = 9.4950(19) angstrom and = 75.47(3)degrees, = 82.21(3)degrees, = 85.56(3)degrees. According to X-ray structure determination both complexes are five coordinate with three bromides and one bidentate ligand; one bromide is set at a semi-bridging position.}}, added-at = {2017-05-10T15:29:29.000+0200}, address = {{4 PARK SQUARE, MILTON PARK, ABINGDON OX14 4RN, OXON, ENGLAND}}, affiliation = {{Alizadeh, R (Reprint Author), Damghan Univ, Sch Chem, Damghan, Iran. Alizadeh, Robabeh; Farshady, Ali Akbar, Damghan Univ, Sch Chem, Damghan, Iran. Amani, Vahid, Islamic Azad Univ, Dept Chem, Shahr e Rey Branch, Tehran, Iran. Khavasi, Hamid Reza, Shaheed Beheshti Univ, Dept Chem, GC, Tehran 198396313, Iran.}}, article-number = {{PII 923382618}}, author = {Alizadeh, Robabeh and Amani, Vahid and Farshady, Ali Akbar and Khavasi, Hamid Reza}, author-email = {{robabeh\_alizadeh@yahoo.com}}, biburl = {https://www.bibsonomy.org/bibtex/270c6c0e120ced27bc2fe8218af48ace3/hkhavasi}, cited-references = {{Ahmadi R, 2008, ACTA CRYSTALLOGR E, V64, pM1233, DOI 10.1107/S1600536808027657. 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Yousefi M, 2009, ACTA CRYSTALLOGR E, V65, pM9, DOI 10.1107/S1600536808040294.}}, doc-delivery-number = {{630OR}}, doi = {{10.1080/00958972.2010.496128}}, funding-acknowledgement = {{Damghan University}}, funding-text = {{Financial support by Damghan University is gratefully acknowledged.}}, interhash = {22928e58c7163924bf6e2cd1e86ba39f}, intrahash = {70c6c0e120ced27bc2fe8218af48ace3}, issn = {{0095-8972}}, journal = {{JOURNAL OF COORDINATION CHEMISTRY}}, journal-iso = {{J. Coord. Chem.}}, keywords = {10-phenanthroline; 2'-bipyridine; 4; 5'-dimethyl-2; 5; 7-diphenyl-1; Crystal structure} {Mercury(II);}, keywords-plus = {{IRON(III) HETEROLIGAND COMPLEXES; METAL-COMPLEXES; MAGNETIC-PROPERTIES; TRIS(4,7-DIPHENYL-1,10-PHENANTHROLINE)RUTHENIUM(II); LIGANDS; DNA; HEXAFLUOROPHOSPHATE; 2,2'-BIPYRIDINE; PHOTOPHYSICS; CHEMISTRY}}, language = {{English}}, number = {{12}}, number-of-cited-references = {{41}}, pages = {{2122-2131}}, publisher = {{TAYLOR \& FRANCIS LTD}}, research-areas = {{Chemistry}}, times-cited = {{9}}, timestamp = {2017-05-10T15:29:29.000+0200}, title = {{Synthesis, characterization, and crystal structure determination of two mercury(II) dimer complexes with 4,7-diphenyl-1,10-phenanthroline, 5,5'-dimethyl-2,2'-bipyridine and bromide}}, type = {{Article}}, unique-id = {{ISI:000280283400011}}, usage-count-last-180-days = {{0}}, usage-count-since-2013 = {{2}}, volume = {{63}}, web-of-science-categories = {{Chemistry, Inorganic \& Nuclear}}, year = {{2010}} }