Rate constants for the reactions of OH, NO3, and O-3 with pinonaldehyde and the structurally related compounds 3-methylbutanal, 3-methylbutan-2-one, cyclobutyl-methylketone, and 2,2,3-trimethyl-cyclobutyl-1-ethanone have been measured at 300 +/- 5 K using on-line Fourier transform infrared spectroscopy. The rate constants obtained for the reactions with pinonaldehyde were: k(OH)=(9.1 +/- 1.8) x 10(-11) cm(3) molecule(-1) s(-1), k(NO3) = (5.4 +/- 1.8) x 10(-14) cm(3) molecule(-1) s(-1), and k(O3) = (8.9 +/- 1.4) x 10(-20) cm(3) molecule(-1) s(-1). The results obtained indicate a chemical lifetime of pinonaldehyde in the troposphere of about two hours under typical daytime conditions, OH = 1.6 x 10(6) molecule cm(-3). (C) 1997 John Wiley and Sons, Inc.
%0 Journal Article
%1 Glasius:1997p2686
%A Glasius, M
%A Calogirou, A
%A Jensen, NR
%A Hjorth, J
%A Nielsen, CJ
%D 1997
%J International Journal of Chemical Kinetics
%K Air, Alpha-Pinene, Beta-Pinene, Co, Constants, Oh, Organic-Compounds Oxidation, Products, Radicals, Rate
%N 7
%P 527--533
%T Kinetic study of gas-phase reactions of pinonaldehyde and structurally related compounds
%U http://www.google.com/search?client=safari&rls=en-us&q=Kinetic+study+of+gas-phase+reactions+of+pinonaldehyde+and+structurally+related+compounds&ie=UTF-8&oe=UTF-8
%V 29
%X Rate constants for the reactions of OH, NO3, and O-3 with pinonaldehyde and the structurally related compounds 3-methylbutanal, 3-methylbutan-2-one, cyclobutyl-methylketone, and 2,2,3-trimethyl-cyclobutyl-1-ethanone have been measured at 300 +/- 5 K using on-line Fourier transform infrared spectroscopy. The rate constants obtained for the reactions with pinonaldehyde were: k(OH)=(9.1 +/- 1.8) x 10(-11) cm(3) molecule(-1) s(-1), k(NO3) = (5.4 +/- 1.8) x 10(-14) cm(3) molecule(-1) s(-1), and k(O3) = (8.9 +/- 1.4) x 10(-20) cm(3) molecule(-1) s(-1). The results obtained indicate a chemical lifetime of pinonaldehyde in the troposphere of about two hours under typical daytime conditions, OH = 1.6 x 10(6) molecule cm(-3). (C) 1997 John Wiley and Sons, Inc.
@article{Glasius:1997p2686,
abstract = {Rate constants for the reactions of OH, NO3, and O-3 with pinonaldehyde and the structurally related compounds 3-methylbutanal, 3-methylbutan-2-one, cyclobutyl-methylketone, and 2,2,3-trimethyl-cyclobutyl-1-ethanone have been measured at 300 +/- 5 K using on-line Fourier transform infrared spectroscopy. The rate constants obtained for the reactions with pinonaldehyde were: k(OH)=(9.1 +/- 1.8) x 10(-11) cm(3) molecule(-1) s(-1), k(NO3) = (5.4 +/- 1.8) x 10(-14) cm(3) molecule(-1) s(-1), and k(O3) = (8.9 +/- 1.4) x 10(-20) cm(3) molecule(-1) s(-1). The results obtained indicate a chemical lifetime of pinonaldehyde in the troposphere of about two hours under typical daytime conditions, [OH] = 1.6 x 10(6) molecule cm(-3). (C) 1997 John Wiley and Sons, Inc.},
added-at = {2010-06-22T19:38:37.000+0200},
affiliation = {COMMISS EUROPEAN COMMUNITIES,JOINT RES CTR,INST ENVIRONM,I-21020 ISPRA,VA,ITALY},
author = {Glasius, M and Calogirou, A and Jensen, NR and Hjorth, J and Nielsen, CJ},
biburl = {https://www.bibsonomy.org/bibtex/22bd30ccd505e2bda3684ebb0e5e5383e/gsmith},
date-added = {2010-03-31 12:06:52 -0400},
date-modified = {2010-03-31 12:06:59 -0400},
interhash = {ca781f09c8e6b96d3d66fbef17ffab2c},
intrahash = {2bd30ccd505e2bda3684ebb0e5e5383e},
journal = {International Journal of Chemical Kinetics},
keywords = {Air, Alpha-Pinene, Beta-Pinene, Co, Constants, Oh, Organic-Compounds Oxidation, Products, Radicals, Rate},
language = {English},
local-url = {file://localhost/Users/geoffreysmith/Documents/Papers/International%20Journal%20of%20Chemical%20Kinetics/1997/International%20Journal%20of%20Chemical%20Kinetics,%2029,%20527-533%201997.pdf},
month = Jan,
number = 7,
pages = {527--533},
pmid = {A1997XF92400007},
rating = {0},
read = {Yes},
timestamp = {2010-06-22T19:39:33.000+0200},
title = {Kinetic study of gas-phase reactions of pinonaldehyde and structurally related compounds},
uri = {papers://E88B624E-D406-46FF-9D95-BB9C1AAE3FDC/Paper/p2686},
url = {http://www.google.com/search?client=safari&rls=en-us&q=Kinetic+study+of+gas-phase+reactions+of+pinonaldehyde+and+structurally+related+compounds&ie=UTF-8&oe=UTF-8},
volume = 29,
year = 1997
}