%0 Journal Article %1 Takahashi:2010p3575 %A Takahashi, Kenshi %A Hurley, Michael D %A Wallington, Timothy J %D 2010 %J International Journal of Chemical Kinetics %K 2-Methyl-3-Buten-2-Ol, Alcohol, Allyl Atoms, Coefficients, Constants, Gas-Phase No3 O-3, Ozone, Pine Radicals, Rate Reactions, %N 3 %P 151--158 %R 10.1002/kin.20475 %T Kinetics and Mechanisms of OH-Initiated Oxidation of Small Unsaturated Alcohols %U http://www3.interscience.wiley.com/journal/123234564/abstract?CRETRY=1&SRETRY=0 %V 42 %X Smog chamber relative rate techniques were used to measure rate coefficients of (5.00 +/- 0.54) x 10(-11). (5.87 +/- 0.63) x 10(-11), and (6.49 +/- 0.82) x 10(-11) cm(3) molecule(-1) s(-1) in 700 Torr air at 296 +/- 1 K for reactions of OH radicals with allyl alcohol, 1-buten-3-ol, and 2-methyl-3-buten-2-ol, respectively, the quoted Uncertainties encompass the extremes of determinations using two different reference compounds The OH-initiated oxidation of allyl alcohol in the presence of NOx gives glycolaldehyde in a molar yield of 0.85 +/- 0.08, the quoted Uncertainty is two standard deviations Oxidation of 2-methyl-3-buten-2-ol gives acetone and glycolaldehyde in molar yields of 0.66 +/- 0.06 and 0.56 +/- 0.05, respectively The reaction of OH radicals with allyl alcohol, 1-buten-3-ol, and 2-methyl-3-buten-2-ol proceeds predominately via addition to the >C=CH2 double bond with most of the addition occurring to the terminal carbon (C) 2010 Wiley Periodicals, Inc Int J Chem Kinet. 42 151-158, 2010

@article{Takahashi:2010p3575, abstract = {Smog chamber relative rate techniques were used to measure rate coefficients of (5.00 +/- 0.54) x 10(-11). (5.87 +/- 0.63) x 10(-11), and (6.49 +/- 0.82) x 10(-11) cm(3) molecule(-1) s(-1) in 700 Torr air at 296 +/- 1 K for reactions of OH radicals with allyl alcohol, 1-buten-3-ol, and 2-methyl-3-buten-2-ol, respectively, the quoted Uncertainties encompass the extremes of determinations using two different reference compounds The OH-initiated oxidation of allyl alcohol in the presence of NOx gives glycolaldehyde in a molar yield of 0.85 +/- 0.08, the quoted Uncertainty is two standard deviations Oxidation of 2-methyl-3-buten-2-ol gives acetone and glycolaldehyde in molar yields of 0.66 +/- 0.06 and 0.56 +/- 0.05, respectively The reaction of OH radicals with allyl alcohol, 1-buten-3-ol, and 2-methyl-3-buten-2-ol proceeds predominately via addition to the >C=CH2 double bond with most of the addition occurring to the terminal carbon (C) 2010 Wiley Periodicals, Inc Int J Chem Kinet. 42 151-158, 2010}, added-at = {2010-06-22T19:38:37.000+0200}, affiliation = {Kyoto Univ, Pioneering Res Unit, Uji, Kyoto 6110011, Japan}, author = {Takahashi, Kenshi and Hurley, Michael D and Wallington, Timothy J}, biburl = {https://www.bibsonomy.org/bibtex/232c889250af605e420aa8300e667f064/gsmith}, date-added = {2010-05-05 16:49:42 -0400}, date-modified = {2010-05-19 13:33:50 -0400}, doi = {10.1002/kin.20475}, interhash = {543b028578756dc54455365191308fd5}, intrahash = {32c889250af605e420aa8300e667f064}, journal = {International Journal of Chemical Kinetics}, keywords = {2-Methyl-3-Buten-2-Ol, Alcohol, Allyl Atoms, Coefficients, Constants, Gas-Phase No3 O-3, Ozone, Pine Radicals, Rate Reactions,}, language = {English}, local-url = {file://localhost/Users/geoffreysmith/Documents/Papers/International%20Journal%20of%20Chemical%20Kinetics/2010/International%20Journal%20of%20Chemical%20Kinetics,%2042,%20151-158%202010.pdf}, month = Jan, number = 3, pages = {151--158}, pmid = {000274937700002}, rating = {0}, timestamp = {2010-06-22T19:39:37.000+0200}, title = {Kinetics and Mechanisms of OH-Initiated Oxidation of Small Unsaturated Alcohols}, uri = {papers://E88B624E-D406-46FF-9D95-BB9C1AAE3FDC/Paper/p3575}, url = {http://www3.interscience.wiley.com/journal/123234564/abstract?CRETRY=1&SRETRY=0}, volume = 42, year = 2010 }