%0 Journal Article %1 Cuevas:2004p3367 %A Cuevas, CA %A Notario, A %A Martinez, E %A Albaladejo, J %D 2004 %J Physical Chemistry Chemical Physics %K Absorption-Spectra Acetone, Atoms, Chlorine Constants, Et-Al, Gas-Phase Laser-Photolysis Mechanism, Oh Radical Radicals, Rate Reactions, Technique, Uv %N 9 %P 2230--2236 %R 10.1039/b313587j %T A kinetic study of the reaction of Cl with a series of linear and ramified ketones as a function of temperature %U http://www.rsc.org/publishing/journals/CP/article.asp?doi=b313587j %V 6 %X The reactions of Cl atoms with 2,3-butadione (k(l)), 2-butanone (k(2)), 2-pentanone (k(3)) 2-hexanone (k(4)), 3-methyl-2-butanone (k(5)) 4-methyl-2-pentanone (k(6)) and 5-methyl-2-hexanone (k(7)) were investigated for the first time as a function of temperature (266-380 K), over the pressure range 20-200 Torr, using pulsed laser photolysis-resonance fluorescence (PLP-RF). The Arrhenius expressions for the seven reactions are proposed. The temperature dependence of the studied reactions is discussed; the reaction of Cl atoms with 2,3-butadione exhibits a positive temperature dependence whereas the corresponding reactions with 2-pentanone, 2-hexanone, 4-methyl-2-pentanone and 5-methyl-2-hexanone exhibit a negative temperature dependence and those with 2-butanone and 3-methyl-2-butanone shows only a slightly positive and a negative temperature dependence, respectively. Finally, the results and atmospheric implications are discussed and compared with the reactivity towards the OH radical.

@article{Cuevas:2004p3367, abstract = {The reactions of Cl atoms with 2,3-butadione (k(l)), 2-butanone (k(2)), 2-pentanone (k(3)) 2-hexanone (k(4)), 3-methyl-2-butanone (k(5)) 4-methyl-2-pentanone (k(6)) and 5-methyl-2-hexanone (k(7)) were investigated for the first time as a function of temperature (266-380 K), over the pressure range 20-200 Torr, using pulsed laser photolysis-resonance fluorescence (PLP-RF). The Arrhenius expressions for the seven reactions are proposed. The temperature dependence of the studied reactions is discussed; the reaction of Cl atoms with 2,3-butadione exhibits a positive temperature dependence whereas the corresponding reactions with 2-pentanone, 2-hexanone, 4-methyl-2-pentanone and 5-methyl-2-hexanone exhibit a negative temperature dependence and those with 2-butanone and 3-methyl-2-butanone shows only a slightly positive and a negative temperature dependence, respectively. Finally, the results and atmospheric implications are discussed and compared with the reactivity towards the OH radical.}, added-at = {2010-06-22T19:38:37.000+0200}, affiliation = {Univ Castilla La Mancha, Dept Quim Fis, Fac CC Quim, E-13071 Ciudad Real, Spain}, author = {Cuevas, CA and Notario, A and Martinez, E and Albaladejo, J}, biburl = {https://www.bibsonomy.org/bibtex/23379603e96cb4d10b48720a6424ea289/gsmith}, date-added = {2010-05-04 15:13:17 -0400}, date-modified = {2010-05-04 15:13:29 -0400}, doi = {10.1039/b313587j}, interhash = {3835329858ec1b2cd34d924a73ffa041}, intrahash = {3379603e96cb4d10b48720a6424ea289}, journal = {Physical Chemistry Chemical Physics}, keywords = {Absorption-Spectra Acetone, Atoms, Chlorine Constants, Et-Al, Gas-Phase Laser-Photolysis Mechanism, Oh Radical Radicals, Rate Reactions, Technique, Uv}, language = {English}, local-url = {file://localhost/Users/geoffreysmith/Documents/Papers/Physical%20Chemistry%20Chemical%20Physics/2004/Physical%20Chemistry%20Chemical%20Physics,%206,%202230-2236%202004.pdf}, month = Jan, number = 9, pages = {2230--2236}, pmid = {000221886100046}, rating = {0}, timestamp = {2010-06-22T19:38:51.000+0200}, title = {A kinetic study of the reaction of Cl with a series of linear and ramified ketones as a function of temperature}, uri = {papers://E88B624E-D406-46FF-9D95-BB9C1AAE3FDC/Paper/p3367}, url = {http://www.rsc.org/publishing/journals/CP/article.asp?doi=b313587j}, volume = 6, year = 2004 }