Cobalt Catalysed Autoxidation of Dissolved Sulfur Dioxide in the Atmospheric Aqueous Phase
D. Kumar. CENTRAL ASIAN JOURNAL OF THEORETICAL AND APPLIED SCIENCE, 4 (5):
201-212(May 2023)
Abstract
Catalytic oxidation are processes that rely on catalysts to introduce oxygen into organic and inorganic compounds. Many applications, including the focus of this article, involve oxidation by oxygen. Such processes are conducted on a large scale for the remediation of pollutants, production of valuable chemicals, and the production of energy.1 The common mechanism is a free radical chain reaction, where the addition of oxygen gives rise to hydroperoxides and their associated peroxy radicals (ROO•).5 Typically, an induction period is seen at the start where there is little activity; this is followed by a gradually accelerating take-up of oxygen, giving an autocatalytic reaction which can only be kept in check by the use of antioxidants. Unsaturated compounds are the most strongly effected but many organic materials will oxidise in this way given time. Sulfur dioxide (IUPAC-recommended spelling) or sulphur dioxide (traditional Commonwealth English) is the chemical compound with the formula SO2. It is a toxic gas responsible for the odor of burnt matches. It is released naturally by volcanic activity and is produced as a by-product of copper extraction and the burning of sulfur-bearing fossil fuels.8.
%0 Journal Article
%1 noauthororeditor
%A Kumar, Dr. Manoj
%D 2023
%J CENTRAL ASIAN JOURNAL OF THEORETICAL AND APPLIED SCIENCE
%K antioxidants, aqueous atmospheric autoxidation, catalysts cobalt, dioxide, phasefree radical, sulphur
%N 5
%P 201-212
%T Cobalt Catalysed Autoxidation of Dissolved Sulfur Dioxide in the Atmospheric Aqueous Phase
%U https://cajotas.centralasianstudies.org/index.php/CAJOTAS/article/view/1184/1241
%V 4
%X Catalytic oxidation are processes that rely on catalysts to introduce oxygen into organic and inorganic compounds. Many applications, including the focus of this article, involve oxidation by oxygen. Such processes are conducted on a large scale for the remediation of pollutants, production of valuable chemicals, and the production of energy.1 The common mechanism is a free radical chain reaction, where the addition of oxygen gives rise to hydroperoxides and their associated peroxy radicals (ROO•).5 Typically, an induction period is seen at the start where there is little activity; this is followed by a gradually accelerating take-up of oxygen, giving an autocatalytic reaction which can only be kept in check by the use of antioxidants. Unsaturated compounds are the most strongly effected but many organic materials will oxidise in this way given time. Sulfur dioxide (IUPAC-recommended spelling) or sulphur dioxide (traditional Commonwealth English) is the chemical compound with the formula SO2. It is a toxic gas responsible for the odor of burnt matches. It is released naturally by volcanic activity and is produced as a by-product of copper extraction and the burning of sulfur-bearing fossil fuels.8.
@article{noauthororeditor,
abstract = {Catalytic oxidation are processes that rely on catalysts to introduce oxygen into organic and inorganic compounds. Many applications, including the focus of this article, involve oxidation by oxygen. Such processes are conducted on a large scale for the remediation of pollutants, production of valuable chemicals, and the production of energy.[1] The common mechanism is a free radical chain reaction, where the addition of oxygen gives rise to hydroperoxides and their associated peroxy radicals (ROO•).[5] Typically, an induction period is seen at the start where there is little activity; this is followed by a gradually accelerating take-up of oxygen, giving an autocatalytic reaction which can only be kept in check by the use of antioxidants. Unsaturated compounds are the most strongly effected but many organic materials will oxidise in this way given time. Sulfur dioxide (IUPAC-recommended spelling) or sulphur dioxide (traditional Commonwealth English) is the chemical compound with the formula SO2. It is a toxic gas responsible for the odor of burnt matches. It is released naturally by volcanic activity and is produced as a by-product of copper extraction and the burning of sulfur-bearing fossil fuels.[8].},
added-at = {2023-09-23T10:27:15.000+0200},
author = {Kumar, Dr. Manoj},
biburl = {https://www.bibsonomy.org/bibtex/2926a4041fbae51f0fd4cd82a40c90620/centralasian_20},
interhash = {28c612317e009756ae33eb87b89bfa44},
intrahash = {926a4041fbae51f0fd4cd82a40c90620},
issn = {2660-5317},
journal = {CENTRAL ASIAN JOURNAL OF THEORETICAL AND APPLIED SCIENCE},
keywords = {antioxidants, aqueous atmospheric autoxidation, catalysts cobalt, dioxide, phasefree radical, sulphur},
language = {english},
month = may,
number = 5,
pages = {201-212},
timestamp = {2023-09-23T10:27:15.000+0200},
title = {Cobalt Catalysed Autoxidation of Dissolved Sulfur Dioxide in the Atmospheric Aqueous Phase},
url = {https://cajotas.centralasianstudies.org/index.php/CAJOTAS/article/view/1184/1241},
volume = 4,
year = 2023
}