%0 Journal Article %1 ISI:000251087900011 %A Abaee, M. Saeed %A Mojtahedi, Mohammad M. %A Zahedi, M. Mehdi %A Sharifi, Roholah %A Khavasi, Hamidreza %C RUDIGERSTR 14, D-70469 STUTTGART, GERMANY %D 2007 %I GEORG THIEME VERLAG KG %J SYNTHESIS-STUTTGART %K aldol bromide condensation; diethyl etherate; heterocycles} magnesium {thiopyrans; %N 21 %P 3339-3344 %R 10.1055/s-2007-990806 %T Efficient synthesis of novel 3-substituted thiopyran-4-ones %X Synthesis of several 3-substituted thiopyran-4-ones is reported for the first time via aldol condensation of various aromatic aldehydes with dihydrothiopyran-4-one derivatives under very mild conditions using magnesium bromide diethyl etherate and triethylamine. The products were characterized based on spectroscopic and X-ray diffraction experiments.

@article{ISI:000251087900011, abstract = {{Synthesis of several 3-substituted thiopyran-4-ones is reported for the first time via aldol condensation of various aromatic aldehydes with dihydrothiopyran-4-one derivatives under very mild conditions using magnesium bromide diethyl etherate and triethylamine. The products were characterized based on spectroscopic and X-ray diffraction experiments.}}, added-at = {2017-05-10T15:29:29.000+0200}, address = {{RUDIGERSTR 14, D-70469 STUTTGART, GERMANY}}, affiliation = {{Mojtahedi, MM (Reprint Author), Chem \& Chem Engn Res Ctr Iran, Dept Organ Chem, PO Box 14335-186, Tehran, Iran. Chem \& Chem Engn Res Ctr Iran, Dept Organ Chem, Tehran, Iran. Shaheed Beheshti Univ, Dept Chem, Tehran 1983963113, Iran.}}, author = {Abaee, M. Saeed and Mojtahedi, Mohammad M. and Zahedi, M. Mehdi and Sharifi, Roholah and Khavasi, Hamidreza}, author-email = {{mojtahedi@ccerci.ac.ir}}, biburl = {https://www.bibsonomy.org/bibtex/2931ee0e7a1640a2045e11f2f77c71d26/hkhavasi}, cited-references = {{Abaee MS, 2006, ARKIVOC, P48. Abaee MS, 2007, HETEROATOM CHEM, V18, P44, DOI 10.1002/hc.20252. Abaee MS, 2005, ORG LETT, V7, P5893, DOI 10.1021/o1052506y. Abaee MS, 2005, SYNLETT, P2317, DOI 10.1055/s-2005-872656. CHEN CH, 1977, J ORG CHEM, V42, P2777, DOI 10.1021/jo00436a026. Douelle F, 2005, CHEM COMMUN, P660, DOI 10.1039/b415463k. GRANT GTN, 2006, J AM CHEM SOC, V128, P9348. Kansal K.K., 1984, J CHEM SOC P1, P703. KITAGAWA H, 2006, CHEM LETT, P712. LANE S, 1984, J CHEM SOC PERK T 1, P2549, DOI 10.1039/p19840002549. Lucassen ACB, 2004, EUR J ORG CHEM, P74, DOI 10.1002/ejoc.200300166. Mojtahedi MM, 2006, CAN J CHEM, V84, P429, DOI 10.1139/V06-024. Mojtahedi MM, 2006, J MOL CATAL A-CHEM, V250, P6, DOI 10.1016/j.molcata.2006.01.024. Mojtahedi MM, 2007, CATAL COMMUN, V8, P1671, DOI 10.1016/j.catcom.2007.01.030. Mojtahedi MM, 2007, PHOSPHORUS SULFUR, V182, P905, DOI 10.1080/10426500601088697. Poleschner H, 2001, EUR J ORG CHEM, P2477. Rosiak A, 2006, EUR J ORG CHEM, P4044, DOI 10.1002/ejoc.200600372. Tipparaju SK, 2004, SYNLETT, P912, DOI 10.1055/s-2004-820036. ULRICH EA, 2006, SYNTHESIS-STUTTGART, P2139. Wang Y, 2003, ORG LETT, V5, P2747, DOI 10.1021/ol034985b. Ward DE, 2007, SYNTHESIS-STUTTGART, P1584, DOI 10.1055/s-2007-965954. Ward DE, 2004, TETRAHEDRON LETT, V45, P8347, DOI 10.1016/j.tetlet.2004.09.061. Ward DE, 2005, ORG LETT, V7, P1181, DOI 10.1021/ol0501951. Ward DE, 2004, TETRAHEDRON-ASYMMETR, V15, P2425, DOI 10.1016/j.tetasy.2004.06.027. Ward DE, 2004, J ORG CHEM, V69, P4808, DOI 10.1021/jo049626o. Ward DE, 2002, J ORG CHEM, V67, P1618, DOI 10.1021/jo016291r. Ward DE, 1996, SYNLETT, P261. WARD DE, 1993, TETRAHEDRON LETT, V34, P947, DOI 10.1016/S0040-4039(00)77461-2. Ward DE, 1997, CAN J CHEM, V75, P681, DOI 10.1139/v97-082. Ward DE, 1996, CAN J CHEM, V74, P1418, DOI 10.1139/v96-160. Ward DE, 2000, ORG LETT, V2, P3937, DOI 10.1021/010067235. Ward D.E., 2005, ORG LETT, V7, P2631.}}, doc-delivery-number = {{233JT}}, doi = {{10.1055/s-2007-990806}}, interhash = {e951b188b3b334bbde4479190a977efe}, intrahash = {931ee0e7a1640a2045e11f2f77c71d26}, issn = {{0039-7881}}, journal = {{SYNTHESIS-STUTTGART}}, journal-iso = {{Synthesis}}, keywords = {aldol bromide condensation; diethyl etherate; heterocycles} magnesium {thiopyrans;}, keywords-plus = {{DIELS-ALDER REACTIONS; SOLVENT-FREE CONDITIONS; BROMIDE ETHYL ETHERATE; ALDOL REACTIONS; MGBR2-CENTER-DOT-OET2; TETRAHYDRO-4H-THIOPYRAN-4-ONE; CATALYSIS; EPOXIDES; REAGENT; ROUTE}}, language = {{English}}, month = {{NOV 2}}, number = {{21}}, number-of-cited-references = {{32}}, pages = {{3339-3344}}, publisher = {{GEORG THIEME VERLAG KG}}, research-areas = {{Chemistry}}, times-cited = {{20}}, timestamp = {2017-05-10T15:29:29.000+0200}, title = {{Efficient synthesis of novel 3-substituted thiopyran-4-ones}}, type = {{Article}}, unique-id = {{ISI:000251087900011}}, usage-count-last-180-days = {{0}}, usage-count-since-2013 = {{5}}, web-of-science-categories = {{Chemistry, Organic}}, year = {{2007}} }