%0 Journal Article %1 ISI:000277548400008 %A Sabounchei, Seyyed Javad %A Gharacheh, Mohsen Ahmadi %A Khavasi, Hamid Reza %C 4 PARK SQUARE, MILTON PARK, ABINGDON OX14 4RN, OXON, ENGLAND %D 2010 %I TAYLOR & FRANCIS LTD %J JOURNAL OF COORDINATION CHEMISTRY %K Dinuclear Orthopalladated; Single complexes; crystal structure} ylide; {Phosphorus %N 7 %P 1165-1175 %R 10.1080/00958971003728320 %T Synthesis and multinuclear NMR study of Hg(II), Cd(II), and Pd(II) complexes with biphenylmethylenetriphenylphosphorane: X-ray crystal structure of \C6H5C6H4CO\(C6H5)(3)P\CH\HgI2(2) %V 63 %X Reactions of title ylide, \(C6H5)(3)PCHCOC6H4C6H5)\ (BPPPY), with mercury(II) halides in equimolar ratios in methanol yielded dinuclear complexes (BPPPY)HgCl2(2) (1), (BPPPY) HgBr2(2) (2), and (BPPPY)HgI2(2) (3). Reactions of BPPPY with CdCl2 in equimolar ratios gave (BPPPY)CdCl2(2) (4). Reaction of PdCl2 with BPPPY (1/2) in acetonitrile at room temperature gave cis/trans PdCl2\CH(PPh3)COC6H4C6H5\(2) (5). The same reaction at reflux gave the orthopalladated complex Pd\CH\P(2-C6H4)Ph\(COC6H4C6H5)\(mu-Cl)(2) (6) along with the phosphonium salt Ph3PCHCOC6H4C6H5Br. The compounds were characterized by elemental analysis, IR-, H-1-, C-13-, and P-31-NMR spectroscopy. Single crystal X-ray analysis of 3 reveals the centrosymmetric dimeric structure containing the ylide and HgI2. Crystallographic data for 3 are: crystal system, monoclinic; space group, P 2(1)/n, a = 15.7744(7), b = 23.0288(9), c = 20.2867(9) angstrom, beta = 112.237(3)degrees, V = 6821.4(5) angstrom(3), and Z = 1.

@article{ISI:000277548400008, abstract = {{Reactions of title ylide, \{(C6H5)(3)PCHCOC6H4C6H5)\} (BPPPY), with mercury(II) halides in equimolar ratios in methanol yielded dinuclear complexes {[}(BPPPY)HgCl2](2) (1), {[}(BPPPY) HgBr2](2) (2), and {[}(BPPPY)HgI2](2) (3). Reactions of BPPPY with CdCl2 in equimolar ratios gave {[}(BPPPY)CdCl2](2) (4). Reaction of PdCl2 with BPPPY (1/2) in acetonitrile at room temperature gave cis/trans {[}PdCl2\{CH(PPh3)COC6H4C6H5\}(2)] (5). The same reaction at reflux gave the orthopalladated complex {[}Pd\{CH\{P(2-C6H4)Ph\}(COC6H4C6H5)\}(mu-Cl)](2) (6) along with the phosphonium salt {[}Ph3PCHCOC6H4C6H5]Br. The compounds were characterized by elemental analysis, IR-, H-1-, C-13-, and P-31-NMR spectroscopy. Single crystal X-ray analysis of 3 reveals the centrosymmetric dimeric structure containing the ylide and HgI2. Crystallographic data for 3 are: crystal system, monoclinic; space group, P 2(1)/n, a = 15.7744(7), b = 23.0288(9), c = 20.2867(9) angstrom, beta = 112.237(3)degrees, V = 6821.4(5) angstrom(3), and Z = 1.}}, added-at = {2017-05-10T15:29:29.000+0200}, address = {{4 PARK SQUARE, MILTON PARK, ABINGDON OX14 4RN, OXON, ENGLAND}}, affiliation = {{Sabounchei, SJ (Reprint Author), Univ Bu Ali Sina, Fac Chem, Hamadan 65174, Iran. Sabounchei, Seyyed Javad; Gharacheh, Mohsen Ahmadi, Univ Bu Ali Sina, Fac Chem, Hamadan 65174, Iran. Khavasi, Hamid Reza, Shaheed Beheshti Univ, Dept Chem, Tehran 1983963113, Iran.}}, author = {Sabounchei, Seyyed Javad and Gharacheh, Mohsen Ahmadi and Khavasi, Hamid Reza}, author-email = {{jsabounchei@yahoo.co.uk}}, biburl = {https://www.bibsonomy.org/bibtex/2bb4ccd35c6f9773c7d886f8e7d2ff489/hkhavasi}, cited-references = {{ALBANESE JA, 1990, INORG CHEM, V29, P2209, DOI 10.1021/ic00337a007. BALDWIN JC, 1979, INORG CHEM, V18, P686, DOI 10.1021/ic50193a031. 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VICENTE J, 1987, J ORGANOMET CHEM, V333, P129, DOI 10.1016/S0022-328X(00)99038-7.}}, doc-delivery-number = {{594PA}}, doi = {{10.1080/00958971003728320}}, funding-acknowledgement = {{University of Bu-AliSina}}, funding-text = {{We are highly grateful to the University of Bu-AliSina for a grant and Mr Zebarjadian for recording the NMR spectra.}}, interhash = {b5e4eec96c0f6c0a0b74f2490b75a41d}, intrahash = {bb4ccd35c6f9773c7d886f8e7d2ff489}, issn = {{0095-8972}}, journal = {{JOURNAL OF COORDINATION CHEMISTRY}}, journal-iso = {{J. Coord. Chem.}}, keywords = {Dinuclear Orthopalladated; Single complexes; crystal structure} ylide; {Phosphorus}, keywords-plus = {{MERCURY(II) HALIDE-COMPLEXES; STABILIZED PHOSPHORUS YLIDES; SILVER(I) COMPLEXES; MOLECULAR-STRUCTURE; LIGANDS; BENZOYLMETHYLENETRIPHENYLPHOSPHORANE; PALLADIUM(II); COORDINATION; DERIVATIVES; GOLD-(III)}}, language = {{English}}, number = {{7}}, number-of-cited-references = {{40}}, orcid-numbers = {{Ahmadi, Mohsen/0000-0002-7018-0460}}, pages = {{1165-1175}}, publisher = {{TAYLOR \& FRANCIS LTD}}, research-areas = {{Chemistry}}, researcherid-numbers = {{Ahmadi, Mohsen/A-6202-2012}}, times-cited = {{12}}, timestamp = {2017-05-10T15:29:29.000+0200}, title = {{Synthesis and multinuclear NMR study of Hg(II), Cd(II), and Pd(II) complexes with biphenylmethylenetriphenylphosphorane: X-ray crystal structure of {[}\{C6H5C6H4CO\{(C6H5)(3)P\}CH\}HgI2](2)}}, type = {{Article}}, unique-id = {{ISI:000277548400008}}, usage-count-last-180-days = {{0}}, usage-count-since-2013 = {{1}}, volume = {{63}}, web-of-science-categories = {{Chemistry, Inorganic \& Nuclear}}, year = {{2010}} }