Abstract The B-site ordered double perovskite Sr2CaOsO6 has been synthesized by a solid-state reaction under ambient pressure. Sr2CaOsO6 is isostructural to Sr2NaOsO6 and Sr2CaReO6, thus crystallizes in the monoclinic space group P21/n, in contrast to cubic lattice symmetry reported in an earlier publication. The compound remains paramagnetic down to a temperature of 2 K. This finding is of relevance with regard to the high-temperature ferromagnetism observed in Sr3OsO6 thin films and may find interest in view of possible exotic ground states in frustrated magnetic systems.
%0 Journal Article
%1 https://doi.org/10.1002/zaac.202300061
%A Thakur, Gohil S.
%A Schnelle, Walter
%A Jansen, Martin
%D 2023
%J Z Anorg Allg Chem
%K b
%N 18
%P e202300061
%R 10.1002/zaac.202300061
%T Crystal structure and properties of the magnetically frustrated B-site ordered Sr$_2$CaOsO$_6$ double perovskite
%U https://onlinelibrary.wiley.com/doi/abs/10.1002/zaac.202300061
%V 649
%X Abstract The B-site ordered double perovskite Sr2CaOsO6 has been synthesized by a solid-state reaction under ambient pressure. Sr2CaOsO6 is isostructural to Sr2NaOsO6 and Sr2CaReO6, thus crystallizes in the monoclinic space group P21/n, in contrast to cubic lattice symmetry reported in an earlier publication. The compound remains paramagnetic down to a temperature of 2 K. This finding is of relevance with regard to the high-temperature ferromagnetism observed in Sr3OsO6 thin films and may find interest in view of possible exotic ground states in frustrated magnetic systems.
@article{https://doi.org/10.1002/zaac.202300061,
abstract = {Abstract The B-site ordered double perovskite Sr2CaOsO6 has been synthesized by a solid-state reaction under ambient pressure. Sr2CaOsO6 is isostructural to Sr2NaOsO6 and Sr2CaReO6, thus crystallizes in the monoclinic space group P21/n, in contrast to cubic lattice symmetry reported in an earlier publication. The compound remains paramagnetic down to a temperature of 2 K. This finding is of relevance with regard to the high-temperature ferromagnetism observed in Sr3OsO6 thin films and may find interest in view of possible exotic ground states in frustrated magnetic systems.},
added-at = {2023-11-22T18:34:44.000+0100},
author = {Thakur, Gohil S. and Schnelle, Walter and Jansen, Martin},
biburl = {https://www.bibsonomy.org/bibtex/2d195f9b3fcb4f684bf09b8ab6342d1df/ctqmat},
day = 20,
doi = {10.1002/zaac.202300061},
eprint = {https://onlinelibrary.wiley.com/doi/pdf/10.1002/zaac.202300061},
interhash = {2238642e7193a793ff1ed41550af1406},
intrahash = {d195f9b3fcb4f684bf09b8ab6342d1df},
journal = {Z Anorg Allg Chem},
keywords = {b},
month = {07},
number = 18,
pages = {e202300061},
timestamp = {2023-11-22T18:35:14.000+0100},
title = {Crystal structure and properties of the magnetically frustrated B-site ordered Sr$_{\mathbf{2}}$CaOsO$_{\mathbf{6}}$ double perovskite},
url = {https://onlinelibrary.wiley.com/doi/abs/10.1002/zaac.202300061},
volume = 649,
year = 2023
}