%0 Journal Article %1 ISI:000284654600017 %A Kianfar, A. H. %A Zargari, S. %A Khavasi, H. R. %C 233 SPRING ST, NEW YORK, NY 10013 USA %D 2010 %I SPRINGER %J JOURNAL OF THE IRANIAN CHEMICAL SOCIETY %K Cu(II); Electrochemistry} Nickel(II); Schiff base complexes; {Cobalt(II); %N 4 %P 908-916 %T Synthesis and Electrochemistry of M(II) N2O2 Schiff Base Complexes: X-Ray Structure of \NiBis(3-chloroacetylacetone)ethylenediimine\ %V 7 %X The synthesis and characterization of Ni(BCE) and Cu(BCE) (where BCE = bis(3-chloroacetylacetone)ethylenediimine) are described. The coordination geometry of Ni(BCE) was determined by X-ray crystallography. It was found to be planar and four coordinate in the solid state. The electrochemical properties of M(Chel), where M = Co(II), Ni(II) and Cu(II), and Chel = BAE (bis(acetylacetone) ethylenediimine), BBE = bis(benzoylacetone) ethylenediimine, BFE (bis(1,1,1-triflouroacetylacetone) ethylenediimine and BCE ligands were investigated in DMF and DMSO as solvents. The oxidation potentials changed from left to right in the periodic table in the trend: Co < Ni < Cu, while the reduction potentials changed according to the trend: Ni > Co > Cu. The oxidation potentials of M(II) to M(III) (M = Ni and Cu) increased according to the Schiff base ligands in the trend: BAE < BBE < BCE < BFE, while the reduction potentials followed a reverse trend: BAE > BBE > BCE > BFE. The oxidation potentials of M(II) to M(III) increased according to the solvent in the trend: DMSO < DMF.

@article{ISI:000284654600017, abstract = {{The synthesis and characterization of {[}Ni(BCE)] and {[}Cu(BCE)] (where BCE = bis(3-chloroacetylacetone)ethylenediimine) are described. The coordination geometry of {[}Ni(BCE)] was determined by X-ray crystallography. It was found to be planar and four coordinate in the solid state. The electrochemical properties of M(Chel), where M = Co(II), Ni(II) and Cu(II), and Chel = BAE (bis(acetylacetone) ethylenediimine), BBE = bis(benzoylacetone) ethylenediimine, BFE (bis(1,1,1-triflouroacetylacetone) ethylenediimine and BCE ligands were investigated in DMF and DMSO as solvents. The oxidation potentials changed from left to right in the periodic table in the trend: Co < Ni < Cu, while the reduction potentials changed according to the trend: Ni > Co > Cu. The oxidation potentials of M(II) to M(III) (M = Ni and Cu) increased according to the Schiff base ligands in the trend: BAE < BBE < BCE < BFE, while the reduction potentials followed a reverse trend: BAE > BBE > BCE > BFE. The oxidation potentials of M(II) to M(III) increased according to the solvent in the trend: DMSO < DMF.}}, added-at = {2017-05-10T15:29:29.000+0200}, address = {{233 SPRING ST, NEW YORK, NY 10013 USA}}, affiliation = {{Kianfar, AH (Reprint Author), Univ Yasuj, Dept Chem, POB 759187-4934Yasouj, Yasuj, Iran. Kianfar, A. H., Univ Yasuj, Dept Chem, Yasuj, Iran. Zargari, S., Kurdistan Univ, Dept Chem, Sanandaj, Iran. Khavasi, H. R., Shahid Beheshti Univ, Dept Chem, GC, Tehran, Iran.}}, author = {Kianfar, A. H. and Zargari, S. and Khavasi, H. R.}, author-email = {{akianfar@mail.yu.ac.ir}}, biburl = {https://www.bibsonomy.org/bibtex/2fb57c3a68e087ac4406a9f8e33edc7b6/hkhavasi}, cited-references = {{Anthonysamy A, 2005, INORG CHEM COMMUN, V8, P908, DOI 10.1016/j.inoche.2005.06.026. Asadi M, 2005, SYNTH REACT INORG ME, V35, P639, DOI 10.1080/15533170500225441. Azevedo F, 2002, POLYHEDRON, V21, P1695, DOI 10.1016/S0277-5387(02)01025-2. BAHDBAHDE MM, 1993, INORG CHEM, V32, P6122. Bottcher A, 1997, INORG CHEM, V36, P2498, DOI 10.1021/ic961146v. Canali L, 1999, CHEM SOC REV, V28, P85, DOI 10.1039/a806483k. Chandra S, 2005, SPECTROCHIM ACTA A, V61, P437, DOI 10.1016/j.saa.2004.04.018. Chattopadhyay S, 2006, INORG CHIM ACTA, V359, P1367, DOI 10.1016/j.ica.2005.12.011. COSTES JP, 1995, INORG CHIM ACTA, V237, P57, DOI 10.1016/0020-1693(95)04641-L. EICHHORN E, 1993, Z NATURFORSCH B, V48, P418. EICHHORN E, 1992, ANGEW CHEM INT EDIT, V31, P1215, DOI 10.1002/anie.199212151. EICHHORN E, 1994, J ELECTROANAL CHEM, V365, P207, DOI 10.1016/0022-0728(93)03058-W. Eichhorn E, 1997, INORG CHEM, V36, P3307, DOI 10.1021/ic9703336. FRY AJ, 1993, J ORG CHEM, V58, P3496, DOI 10.1021/jo00065a008. GAMMACK R, 1988, ADV INORG CHEM, V32, P297. GARNOVSKII AD, 1993, COORDIN CHEM REV, V126, P1, DOI 10.1016/0010-8545(93)85032-Y. Gollas B, 1996, Z NATURFORSCH B, V51, P388. Isse AA, 1998, J ELECTROANAL CHEM, V444, P241, DOI 10.1016/S0022-0728(97)00572-X. Jager EG, 1997, INORG CHIM ACTA, V255, P295, DOI 10.1016/S0020-1693(96)05377-7. KAPTURKIEWICZ A, 1983, INORG CHIM A-ARTICLE, V69, P247, DOI 10.1016/S0020-1693(00)83581-1. Kianfar AH, 2008, J COORD CHEM, V61, P341, DOI 10.1080/00958970701329217. KWIATKOWSKI E, 1984, INORG CHIM A-ART LET, V82, P101, DOI 10.1016/S0020-1693(00)82545-1. KWIATKOWSKI M, 1992, J CHEM SOC DALTON, P379, DOI 10.1039/dt9920000379. KWIATKOWSKI M, 1990, J CHEM SOC DALTON, P2497, DOI 10.1039/dt9900002497. Marcus Y., 1999, WILEY SERIES SOLUTIO, V4, P151. MCCARTHY PJ, 1955, J AM CHEM SOC, V77, P5820, DOI 10.1021/ja01627a011. Okada T, 1999, J ELECTROCHEM SOC, V146, P2562, DOI 10.1149/1.1391972. Pereira E, 1998, J CHEM SOC DALTON, P629, DOI 10.1039/a705685k. Pletcher D, 1999, J ELECTROANAL CHEM, V464, P168, DOI 10.1016/S0022-0728(99)00015-7. Ray MS, 2003, POLYHEDRON, V22, P617, DOI 10.1016/S0277-5387(02)01435-3. Samide MJ, 1998, J ELECTROANAL CHEM, V443, P95, DOI 10.1016/S0022-0728(97)00460-9. Santos IC, 2000, POLYHEDRON, V19, P655, DOI 10.1016/S0277-5387(00)00300-4. Sarvestani AH, 2005, J CHEM RES-S, P190. Sarvestani AH, 2006, J CHEM RES, P257. Sheldrick G. M., 1997, SHELX 97 PROGRAM CRY. SMITH CW, 1976, CAN J CHEM, V54, P1875, DOI 10.1139/v76-267. SPEISER B, 1995, ANGEW CHEM INT EDIT, V34, P1086, DOI 10.1002/anie.199510861. {*}STOE CIE GMBH, 2005, X RED VES 1 28B PROG. Stoe\&Cie, 2000, X STEP32 VERS 1 07B. Stoe \& Cie, 2005, X AREA VES 1 30 PROG. X-SHAPE, 2004, X SHAPE VES 2 05 PRO. Yaman S.O., 2005, POLYHEDRON, V24, P1821. Yu-Ying Ch., 1981, INORG CHEM, V20, P1885. Zolezzi S, 2002, POLYHEDRON, V21, P55, DOI 10.1016/S0277-5387(01)00960-3. {[}Anonymous], 1995, INT TABLES FOE XRAY.}}, doc-delivery-number = {{685UW}}, interhash = {8f97a449385bc68e77fba33973140d9e}, intrahash = {fb57c3a68e087ac4406a9f8e33edc7b6}, issn = {{1735-207X}}, journal = {{JOURNAL OF THE IRANIAN CHEMICAL SOCIETY}}, journal-iso = {{J. Iran Chem. Soc.}}, keywords = {Cu(II); Electrochemistry} Nickel(II); Schiff base complexes; {Cobalt(II);}, keywords-plus = {{SOLVENT-EXCHANGE-REACTIONS; OXYGENATION CATALYSTS; COPPER(II) COMPLEXES; NICKEL(II) COMPLEXES; ELECTRON-TRANSFER; CRYSTAL-STRUCTURE; 1ST EVIDENCE; LIGANDS; REDUCTION; SPECTROSCOPY}}, language = {{English}}, month = {{DEC}}, number = {{4}}, number-of-cited-references = {{45}}, orcid-numbers = {{zargari, solmaz/0000-0002-6209-2719}}, pages = {{908-916}}, publisher = {{SPRINGER}}, research-areas = {{Chemistry}}, researcherid-numbers = {{zargari, solmaz/J-4311-2016}}, times-cited = {{5}}, timestamp = {2017-05-10T15:29:29.000+0200}, title = {{Synthesis and Electrochemistry of M(II) N2O2 Schiff Base Complexes: X-Ray Structure of \{Ni{[}Bis(3-chloroacetylacetone)ethylenediimine]\}}}, type = {{Article}}, unique-id = {{ISI:000284654600017}}, usage-count-last-180-days = {{1}}, usage-count-since-2013 = {{4}}, volume = {{7}}, web-of-science-categories = {{Chemistry, Multidisciplinary}}, year = {{2010}} }