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A novel 3D supramolecular coordination polymer based on tetranuclear complex of lead(ii) with terephthalic acid and 8-hydroxyquinolin, Pb-4(8-Quin)(4)(Tp)(2)(DMF)(2) (n)

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RUSSIAN JOURNAL OF COORDINATION CHEMISTRY, 38 (9): 646-650 (сентября 2012)
DOI: {10.1134/S1070328412080027}

Аннотация

A novel two-dimensional coordination polymer, Pb-4(8-Quin)(4)(Tp)(2)(DMF)(2) (n) (Tp = terephthalic dianion, 8-Quin = 8-Hydroxyquinolate, and DMF = N,N-dimethylformamide) has been synthesized and characterized by elemental analysis, FT-IR, and single crystal X-ray diffraction. The single crystal X-ray analysis shows that the complex is a two-dimensional (2D) polymer and the dimensionality is further increased to 3D as a result of weak C-HaEuro broken vertical bar pi and C-HaEuro broken vertical bar O interactions.

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