%0 Journal Article %1 liu2018gassolid %A Liu, Zonghao %A Qiu, Longbin %A Juarez-Perez, Emilio J. %A Hawash, Zafer %A Kim, Taehoon %A Jiang, Yan %A Wu, Zhifang %A Raga, Sonia R. %A Ono, Luis K. %A Liu, Shengzhong (Frank) %A Qi, Yabing %D 2018 %J Nature Communications %K gas reaction solid %N 1 %P 3880-- %R 10.1038/s41467-018-06317-8 %T Gas-solid reaction based over one-micrometer thick stable perovskite films for efficient solar cells and modules %U https://doi.org/10.1038/s41467-018-06317-8 %V 9 %X Besides high efficiency, the stability and reproducibility of perovskite solar cells (PSCs) are also key for their commercialization. Herein, we report a simple perovskite formation method to fabricate perovskite films with thickness over 1 μm in ambient condition on the basis of the fast gas−solid reaction of chlorine-incorporated hydrogen lead triiodide and methylamine gas. The resultant thick and smooth chlorine-incorporated perovskite films exhibit full coverage, improved crystallinity, low surface roughness and low thickness variation. The resultant PSCs achieve an average power conversion efficiency of 19.1 ± 0.4% with good reproducibility. Meanwhile, this method enables an active area efficiency of 15.3% for 5 cm × 5 cm solar modules. The un-encapsulated PSCs exhibit an excellent T80 lifetime exceeding 1600 h under continuous operation conditions in dry nitrogen environment.

@article{liu2018gassolid, abstract = {Besides high efficiency, the stability and reproducibility of perovskite solar cells (PSCs) are also key for their commercialization. Herein, we report a simple perovskite formation method to fabricate perovskite films with thickness over 1 μm in ambient condition on the basis of the fast gas−solid reaction of chlorine-incorporated hydrogen lead triiodide and methylamine gas. The resultant thick and smooth chlorine-incorporated perovskite films exhibit full coverage, improved crystallinity, low surface roughness and low thickness variation. The resultant PSCs achieve an average power conversion efficiency of 19.1 ± 0.4% with good reproducibility. Meanwhile, this method enables an active area efficiency of 15.3% for 5 cm × 5 cm solar modules. The un-encapsulated PSCs exhibit an excellent T80 lifetime exceeding 1600 h under continuous operation conditions in dry nitrogen environment.}, added-at = {2018-09-27T10:15:09.000+0200}, author = {Liu, Zonghao and Qiu, Longbin and Juarez-Perez, Emilio J. and Hawash, Zafer and Kim, Taehoon and Jiang, Yan and Wu, Zhifang and Raga, Sonia R. and Ono, Luis K. and Liu, Shengzhong (Frank) and Qi, Yabing}, biburl = {https://www.bibsonomy.org/bibtex/28601f2c3c6af3634d9ffb2670416b20d/sere}, doi = {10.1038/s41467-018-06317-8}, interhash = {36fc4bd821a100102caf85c2b7d4838e}, intrahash = {8601f2c3c6af3634d9ffb2670416b20d}, issn = {20411723}, journal = {Nature Communications}, keywords = {gas reaction solid}, number = 1, pages = {3880--}, refid = {Liu2018}, timestamp = {2018-09-27T10:15:09.000+0200}, title = {Gas-solid reaction based over one-micrometer thick stable perovskite films for efficient solar cells and modules}, url = {https://doi.org/10.1038/s41467-018-06317-8}, volume = 9, year = 2018 }