%0 Journal Article %1 Krumgalz1996a %A Krumgalz, B. S. %A Pogorelsky, R. %A Pitzer, K. S. %D 1996 %J JOURNAL OF PHYSICAL AND Chemical REFERENCE DATA %K 1 298.15 ALKALINE-EARTH APPARENT ATM CHLORIDES; COEFFICIENTS; DIFFUSION-COEFFICIENTS; HEAT-CAPACITIES; K; MOLAL MUTUAL OSMOTIC PROPERTIES; PVT SODIUM-CHLORIDE SOLUTIONS; TRANSPORT-COEFFICIENTS; VOLUMES; %N 2 %P 663--689 %T Volumetric properties of single aqueous electrolytes from zero to saturation concentration at 298.15 degrees K represented by Pitzer's ion-interaction equations %V 25 %X The ion interaction approach developed by Fitter allows the prediction of various thermodynamic characteristics of multiple-solute electrolyte solutions, if the respective parameters for each type of single-solute electrolyte solution are known. The present paper discusses the Fitter approach to the calculations of the volumetric properties of single-solute electrolyte solutions. The databases for the densities and the apparent molal volumes versus concentrations were created at 298.15 degrees K using essentially all published relevant data for each single-solute electrolyte solution. Poor experimental data were discarded by a statistical treatment applied to these databases. Proper treatment of all good quality density and apparent molal volume data, in a wide range of concentrations from infinite dilution through saturation, allowed us to evaluate the volumetric ion interaction parameters (<(V)over bar (0)(MX)>, beta(MX)((0)V), beta(MX)((1)V), beta(MX)((2)V), and C-MX(V)) at 298.15 degrees K for 102 electrolytes. Strong linear relationships between the beta(MX)((1)V), beta(MX)((2)V), or C-MX(V), and beta(MX)((0)V) volumetric ion interaction parameters were observed for all analyzed solutes with slopes depending on the solute valency types. (C) 1996 American Institute of Physics and American Chemical Society.

@article{Krumgalz1996a, abstract = {The ion interaction approach developed by Fitter allows the prediction of various thermodynamic characteristics of multiple-solute electrolyte solutions, if the respective parameters for each type of single-solute electrolyte solution are known. The present paper discusses the Fitter approach to the calculations of the volumetric properties of single-solute electrolyte solutions. The databases for the densities and the apparent molal volumes versus concentrations were created at 298.15 degrees K using essentially all published relevant data for each single-solute electrolyte solution. Poor experimental data were discarded by a statistical treatment applied to these databases. Proper treatment of all good quality density and apparent molal volume data, in a wide range of concentrations from infinite dilution through saturation, allowed us to evaluate the volumetric ion interaction parameters (<(V)over bar (0)(MX)>, beta(MX)((0)V), beta(MX)((1)V), beta(MX)((2)V), and C-MX(V)) at 298.15 degrees K for 102 electrolytes. Strong linear relationships between the beta(MX)((1)V), beta(MX)((2)V), or C-MX(V), and beta(MX)((0)V) volumetric ion interaction parameters were observed for all analyzed solutes with slopes depending on the solute valency types. (C) 1996 American Institute of Physics and American Chemical Society.}, added-at = {2009-11-03T20:21:25.000+0100}, author = {Krumgalz, B. S. and Pogorelsky, R. and Pitzer, K. 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TANAKA K, 1991, Z NATURFORSCH A, V46, P141 ; TRIMBLE HM, 1922, J AM CHEM SOC, V44, P451 ; VASILEV YA, 1973, RUSS J PHYS CHEM, V47, P1570 ; VASLOW F, 1966, ORNLTM1438 ; VASLOW F, 1969, J PHYS CHEM-US, V73, P3745 ; VOROBEV AF, 1982, ZH FIZ KHIM, V56, P1021 ; WEINGARTNER H, 1984, J PHYS CHEM-US, V88, P2173 ; WIRTH HE, 1937, J AM CHEM SOC, V59, P2549 ; WIRTH HE, 1940, J AM CHEM SOC, V62, P1128}, interhash = {448fad34e0d4df999f23a611d9cb8651}, intrahash = {4c7bcf15e17d4749e8ad61985356bc13}, journal = {JOURNAL OF PHYSICAL AND Chemical REFERENCE DATA}, keywords = {1 298.15 ALKALINE-EARTH APPARENT ATM CHLORIDES; COEFFICIENTS; DIFFUSION-COEFFICIENTS; HEAT-CAPACITIES; K; MOLAL MUTUAL OSMOTIC PROPERTIES; PVT SODIUM-CHLORIDE SOLUTIONS; TRANSPORT-COEFFICIENTS; VOLUMES;}, number = 2, owner = {svance}, pages = {663--689}, timestamp = {2009-11-03T20:21:56.000+0100}, title = {Volumetric properties of single aqueous electrolytes from zero to saturation concentration at 298.15 degrees K represented by Pitzer's ion-interaction equations}, volume = 25, year = 1996 }