%0 Journal Article %1 ISI:000281322400008 %A Al-Hashemi, Radhiya %A Safari, Nasser %A Amani, Saeid %A Amani, Vahid %A Abedi, Anita %A Khavasi, Hamid Reza %A Ng, Seik Weng %C 4 PARK SQUARE, MILTON PARK, ABINGDON OX14 4RN, OXON, ENGLAND %D 2010 %I TAYLOR & FRANCIS LTD %J JOURNAL OF COORDINATION CHEMISTRY %K 2'-Dimethyl-4; 2; 4'-bithiazole; Crystal Dimethyl Terephthalic acid; structure} sulfoxide; {Copper; %N 18 %P 3207-3217 %R 10.1080/00958972.2010.509794 %T Synthesis, characterization, and crystal structure determination of two copper(II) complexes: Cu(dm4bt)Cl2(DMSO) and \Cu(dm4bt)(H2O)(tpht)\ center dot H2On %V 63 %X Copper complexes, Cu(dm4bt)Cl2(DMSO) (1) and \Cu(dm4bt)(H2O)(tpht)\ H2On (2) (dm4bt, 2,2'-dimethyl-4,4'-bithiazole; tpht, terephthalate), have been synthesized and their crystal structures were determined by X-ray crystallography. Complex 1 was prepared from a reaction of CuCl2 2H2O with dm4bt and terephthalic acid in a mixture of methanol, water, and DMSO. Complex 2 was prepared from a reaction of CuCl2 2H2O with dm4bt, terephthalic acid, and ethylene diamine in a mixture of methanol and water. The two complexes were characterized by IR, UV-Vis spectroscopy, and single-crystal structure. Complex 2 was also characterized by electron paramagnetic resonance spectra. Complex 1 is a monomer while 2 is a coordination polymer. This copper tpht polymer has a cis-configuration of tpht rings opposed to zigzag chains with anti-configuration usually reported in the literature.

@article{ISI:000281322400008, abstract = {{Copper complexes, {[}Cu(dm4bt)Cl2(DMSO)] (1) and {[}\{Cu(dm4bt)(H2O)(tpht)\} H2O]n (2) (dm4bt, 2,2'-dimethyl-4,4'-bithiazole; tpht, terephthalate), have been synthesized and their crystal structures were determined by X-ray crystallography. Complex 1 was prepared from a reaction of CuCl2 2H2O with dm4bt and terephthalic acid in a mixture of methanol, water, and DMSO. Complex 2 was prepared from a reaction of CuCl2 2H2O with dm4bt, terephthalic acid, and ethylene diamine in a mixture of methanol and water. The two complexes were characterized by IR, UV-Vis spectroscopy, and single-crystal structure. Complex 2 was also characterized by electron paramagnetic resonance spectra. Complex 1 is a monomer while 2 is a coordination polymer. This copper tpht polymer has a cis-configuration of tpht rings opposed to zigzag chains with anti-configuration usually reported in the literature.}}, added-at = {2017-05-10T15:29:29.000+0200}, address = {{4 PARK SQUARE, MILTON PARK, ABINGDON OX14 4RN, OXON, ENGLAND}}, affiliation = {{Safari, N (Reprint Author), Shahid Beheshti Univ, Dept Chem, GC, Tehran 1983963113, Iran. Al-Hashemi, Radhiya; Safari, Nasser; Amani, Vahid; Khavasi, Hamid Reza, Shahid Beheshti Univ, Dept Chem, GC, Tehran 1983963113, Iran. Amani, Saeid, Arak Univ, Dept Chem, Arak 38156, Iran. Abedi, Anita, Islamic Azad Univ, Dept Chem, N Tehran Branch, Tehran, Iran. Ng, Seik Weng, Univ Malaya, Dept Chem, Kuala Lumpur 50603, Malaysia.}}, article-number = {{PII 925641497}}, author = {Al-Hashemi, Radhiya and Safari, Nasser and Amani, Saeid and Amani, Vahid and Abedi, Anita and Khavasi, Hamid Reza and Ng, Seik Weng}, author-email = {{n-safari@cc.sbu.ac.ir}}, biburl = {https://www.bibsonomy.org/bibtex/2b9d5b4ac405ed05fd8f638795e2a2440/hkhavasi}, cited-references = {{ABUHIJLEH AL, 1993, INORG CHIM ACTA, V209, P187, DOI 10.1016/S0020-1693(00)85140-3. ADDISON AW, 1984, J CHEM SOC DALTON, P1349, DOI 10.1039/dt9840001349. Al-Hashemi R, 2009, J COORD CHEM, V62, P2909, DOI 10.1080/00958970902948138. Amani V, 2007, POLYHEDRON, V26, P4257, DOI 10.1016/j.poly.2007.05.050. Baca SG, 2004, J SOLID STATE CHEM, V177, P2841, DOI 10.1016/j.jssc.2004.05.001. Banerjee S, 2005, POLYHEDRON, V24, P2963, DOI 10.1016/j.poly.2005.06.038. Boudalis AK, 2004, POLYHEDRON, V23, P1271, DOI 10.1016/j.poly.2004.02.008. Bu PY, 2003, J CHEM CRYSTALLOGR, V33, P257, DOI 10.1023/A:1023877026346. Chen HJ, 2006, INORG CHEM COMMUN, V9, P300, DOI 10.1016/j.inoche.2005.12.001. CHERIF NB, 1995, ACTA CRYSTALLOGR C, V51, P72. Company A, 2006, INORG CHEM, V45, P2501, DOI 10.1021/ic051759k. Dhar S, 2004, DALTON T, P4180, DOI 10.1039/b414639e. DREW MGB, 1983, POLYHEDRON, V2, P269, DOI 10.1016/S0277-5387(00)83912-1. Du M, 2002, INORG CHIM ACTA, V335, P136, DOI 10.1016/S0020-1693(02)00810-1. GARCIA FJB, 2005, Z ANORG ALLG CHEM, V631, P1898. HATHAWAY BJ, 1970, COORDIN CHEM REV, V5, P1, DOI 10.1016/S0010-8545(00)80073-9. Janiak C, 1999, J CHEM SOC DALTON, P3121, DOI 10.1039/a904829d. Jiang LM, 2002, POLYMER, V43, P1563, DOI 10.1016/S0032-3861(01)00698-X. Jiang LM, 2005, POLYM ADVAN TECHNOL, V16, P646, DOI 10.1002/pat.622. Khavasi HR, 2008, POLYHEDRON, V27, P1848, DOI 10.1016/j.poly.2008.02.029. Li LC, 2001, J MOL STRUCT, V597, P157, DOI 10.1016/S0022-2860(01)00594-4. Li YT, 2008, J INORG BIOCHEM, V102, P1790, DOI 10.1016/j.jinorgbio.2008.05.011. Lin DD, 2005, J COORD CHEM, V58, P605, DOI 10.1080/00958970500039116. Liu FQ, 2006, INORG CHIM ACTA, V359, P1524, DOI 10.1016/j.ica.2005.12.035. Meng QG, 2008, ACTA CRYSTALLOGR E, V64, pM133, DOI 10.1107/S1600536807065051. Moncol J, 2007, Z ANORG ALLG CHEM, V633, P298, DOI 10.1002/zaac.200600183. Nakamoto K., 1997, INFRARED RAMAN SPE B. Neels A, 1999, INORG CHEM, V38, P6164, DOI 10.1021/ic990843v. Notash B, 2008, J ORGANOMET CHEM, V693, P3553, DOI 10.1016/j.jorganchem.2008.08.027. Notash B, 2009, J COORD CHEM, V62, P1638, DOI 10.1080/00958970802672978. Prince E., 2004, INT TABLES XRAY CRYS, VC, P577. Ren YW, 2005, STRUCT CHEM, V16, P439, DOI 10.1007/s11224-005-6353-5. Rogan J, 2004, J SERB CHEM SOC, V69, P353, DOI 10.2298/JSC0405353R. Sasaki H, 1996, CHEM PHARM BULL, V44, P1761. Sheldrick GM, 2008, ACTA CRYSTALLOGR A, V64, P112, DOI 10.1107/S0108767307043930. Sheldrick G. M., 1996, SADABS. Solomon EI, 1996, CHEM REV, V96, P2563, DOI 10.1021/cr950046o. {[}Anonymous], 2005, X AREA PROGR ACQ AN. {[}Anonymous], 2004, X SHAPE PROGR CRYST. {[}Anonymous], 2005, X RED PROGR DAT RED. Sun DF, 2001, J CHEM SOC DALTON, P2335, DOI 10.1039/b102888j. Sun WL, 1997, J APPL POLYM SCI, V64, P2309, DOI 10.1002/(SICI)1097-4628(19970620)64:12<2309::AID-APP6>3.0.CO;2-P. Tian YN, 1996, POLYHEDRON, V15, P2771. Tian YN, 1997, J COORD CHEM, V41, P223, DOI 10.1080/00958979708023573. Wang YY, 2002, TRANSIT METAL CHEM, V27, P145, DOI 10.1023/A:1013994622329. WEAVER JA, 1970, INORG CHEM, V9, P268, DOI 10.1021/ic50084a017. Wen YH, 2005, INORG CHIM ACTA, V358, P3347, DOI 10.1016/j.ica.2005.05.004. Wen YH, 2007, ACTA CRYSTALLOGR E, V63, pM1865, DOI 10.1107/S1600536807027663. Weng JA, 2000, MACROMOL RAPID COMM, V21, P1099, DOI 10.1002/1521-3927(20001001)21:15<1099::AID-MARC1099>3.0.CO;2-6. XU SP, 2006, Z KRIST-NEW CRYST ST, V221, P1. Zhai B, 2006, INORG CHEM COMMUN, V9, P1293, DOI 10.1016/j.inoche.2006.08.002. Zheng H, 1997, INORG CHIM ACTA, V263, P301, DOI 10.1016/S0020-1693(97)05659-4.}}, doc-delivery-number = {{643TP}}, doi = {{10.1080/00958972.2010.509794}}, funding-acknowledgement = {{Graduate Study Councils of the Shahid Beheshti University {[}600/1207]}}, funding-text = {{We thank the Graduate Study Councils of the Shahid Beheshti University for the financial support (Project 600/1207).}}, interhash = {48f232df5f68bbfa55d098961654245a}, intrahash = {b9d5b4ac405ed05fd8f638795e2a2440}, issn = {{0095-8972}}, journal = {{JOURNAL OF COORDINATION CHEMISTRY}}, journal-iso = {{J. Coord. Chem.}}, keywords = {2'-Dimethyl-4; 2; 4'-bithiazole; Crystal Dimethyl Terephthalic acid; structure} sulfoxide; {Copper;}, keywords-plus = {{TUMOR-INHIBITING PROPERTIES; MAGNETIC-PROPERTIES; MOLECULAR-STRUCTURE; COORDINATION POLYMERS; HYDROTHERMAL SYNTHESES; CADMIUM(II) COMPLEXES; TERMINAL LIGAND; MIXED-LIGANDS; ZIGZAG CHAIN; SCHIFF-BASE}}, language = {{English}}, number = {{18}}, number-of-cited-references = {{52}}, orcid-numbers = {{, Anita/0000-0001-7562-6241}}, pages = {{3207-3217}}, publisher = {{TAYLOR \& FRANCIS LTD}}, research-areas = {{Chemistry}}, times-cited = {{5}}, timestamp = {2017-05-10T15:29:29.000+0200}, title = {{Synthesis, characterization, and crystal structure determination of two copper(II) complexes: {[}Cu(dm4bt)Cl2(DMSO)] and {[}\{Cu(dm4bt)(H2O)(tpht)\} center dot H2O]n}}, type = {{Article}}, unique-id = {{ISI:000281322400008}}, usage-count-last-180-days = {{3}}, usage-count-since-2013 = {{5}}, volume = {{63}}, web-of-science-categories = {{Chemistry, Inorganic \& Nuclear}}, year = {{2010}} }