%0 Journal Article %1 LeCalve:1998p3380 %A Calve, S Le %A Hitier, D %A Bras, G Le %A Mellouki, A %D 1998 %J Journal of Physical Chemistry A %K Atmospheric Constants, Ethers, Gas-Phase Hydrocarbons, Hydroxyl Mechanism, Organic-Compounds, Oxygenated Photo-Oxidation, Radicals, Rate Reactions Reactivity, %N 24 %P 4579--4584 %T Kinetic studies of OH reactions with a series of ketones %U http://www.google.com/search?client=safari&rls=en-us&q=Kinetic+studies+of+OH+reactions+with+a+series+of+ketones&ie=UTF-8&oe=UTF-8 %V 102 %X Absolute rate constants have been measured for the gas-phase reactions of hydroxyl radicals with a series of ketones: acetone (k(1)), 2-butanone (k(2)), 3-methyl 2-butanone (k(3)), 4-methyl 2-pentanone (k(4)), and 5-methyl 2-hexanone (k(5)) Experiments were carried out using the pulsed laser photolysis-laser-induced fluorescence technique over the temperature range 243-372 K. The obtained kinetic data were used to derive the Arrhenius expressions: k(1) = (1.25 +/- 0.22) x 10(-12) exp-(561 +/- 57)/T; k(2) = (1.19 +/- 0.18) x 10(-12) exp-(60 +/- 61)/T; k(3) = (1.58 +/- 0.35) x 10(-12) exp(193 +/- 65)/T; k(4 ) = (0.759 +/- 0.126) x 10(-12) exp(834 +/- 46)/T, and k(5) = (1.33 +/- 0.63) x 10(-12) exp(649 +/- 140)/T (in units of cm(3) molecule(-1) s(-1)). At room temperature, the rate constants obtained (in units of 10(-12 )cm(3) molecule(-1) s(-1)) were as follows: acetone (0.184 +/- 0.024); 2-butanone (1.19 +/- 0.18); 5-methyl 2-butanone (2.87 +/- 0.29); 4-methyl 2-pentanone (12.1 +/- 0.9); and 5-methyl 2-hexanone (10.3 +/- 1.0). Our results are compared with the previous determinations and discussed in terms of structure-reactivity relationships.

@article{LeCalve:1998p3380, abstract = {Absolute rate constants have been measured for the gas-phase reactions of hydroxyl radicals with a series of ketones: acetone (k(1)), 2-butanone (k(2)), 3-methyl 2-butanone (k(3)), 4-methyl 2-pentanone (k(4)), and 5-methyl 2-hexanone (k(5)) Experiments were carried out using the pulsed laser photolysis-laser-induced fluorescence technique over the temperature range 243-372 K. The obtained kinetic data were used to derive the Arrhenius expressions: k(1) = (1.25 +/- 0.22) x 10(-12) exp[-(561 +/- 57)/T]; k(2) = (1.19 +/- 0.18) x 10(-12) exp[-(60 +/- 61)/T]; k(3) = (1.58 +/- 0.35) x 10(-12) exp[(193 +/- 65)/T]; k(4 ) = (0.759 +/- 0.126) x 10(-12) exp[(834 +/- 46)/T], and k(5) = (1.33 +/- 0.63) x 10(-12) exp[(649 +/- 140)/T] (in units of cm(3) molecule(-1) s(-1)). At room temperature, the rate constants obtained (in units of 10(-12 )cm(3) molecule(-1) s(-1)) were as follows: acetone (0.184 +/- 0.024); 2-butanone (1.19 +/- 0.18); 5-methyl 2-butanone (2.87 +/- 0.29); 4-methyl 2-pentanone (12.1 +/- 0.9); and 5-methyl 2-hexanone (10.3 +/- 1.0). Our results are compared with the previous determinations and discussed in terms of structure-reactivity relationships.}, added-at = {2010-06-22T19:38:37.000+0200}, affiliation = {CNRS, Lab Combust {\&} Syst React, F-45071 Orleans 2, France}, author = {Calve, S Le and Hitier, D and Bras, G Le and Mellouki, A}, biburl = {https://www.bibsonomy.org/bibtex/2c0600eef3d8f8b913d241c13c84445b2/gsmith}, date-added = {2010-05-03 16:05:34 -0400}, date-modified = {2010-05-03 16:05:48 -0400}, interhash = {4f479e5a93f1766c4b568c983c29eac8}, intrahash = {c0600eef3d8f8b913d241c13c84445b2}, journal = {Journal of Physical Chemistry A}, keywords = {Atmospheric Constants, Ethers, Gas-Phase Hydrocarbons, Hydroxyl Mechanism, Organic-Compounds, Oxygenated Photo-Oxidation, Radicals, Rate Reactions Reactivity,}, language = {English}, local-url = {file://localhost/Users/geoffreysmith/Documents/Papers/Journal%20of%20Physical%20Chemistry%20A/1998/Journal%20of%20Physical%20Chemistry%20A,%20102,%204579-4584%201998.pdf}, month = Jan, number = 24, pages = {4579--4584}, pmid = {000074285000023}, rating = {0}, timestamp = {2010-06-22T19:39:05.000+0200}, title = {Kinetic studies of OH reactions with a series of ketones}, uri = {papers://E88B624E-D406-46FF-9D95-BB9C1AAE3FDC/Paper/p3380}, url = {http://www.google.com/search?client=safari&rls=en-us&q=Kinetic+studies+of+OH+reactions+with+a+series+of+ketones&ie=UTF-8&oe=UTF-8}, volume = 102, year = 1998 }