Zusammenfassung
The optical properties of epitaxial BiFeO 3 thin films have been characterized in the visible range.
Variable temperature spectra show an absorption onset near 2.17 eV, a direct gap ͑2.667Ϯ 0.005 eV
at 300 K͒, and charge transfer excitations at higher energy. Additionally, we report
photoconductivity in BiFeO 3 films under illumination from a 100 mW/ cm 2 white light source. A
direct correlation is observed between the magnitude of the photoconductivity and postgrowth
cooling pressure. Dark conductivities increased by an order of magnitude when comparing films
cooled in 760 and 0.1 Torr. Large increases in photoconductivity are observed in light.
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