Incollection,

Properties of fluids under strong confinement: a mode coupling approach

, , and .
Abstract Book of the XXIII IUPAP International Conference on Statistical Physics, Genova, Italy, (9-13 July 2007)

Abstract

When a fluid is confined between two molecularly smooth surfaces separated by a few molecular layers, it shows an apparent shear viscosity over a million times its macroscopic value and strong shear thinning at remarkably low shear rates. We extend the mode-coupling theory of the viscosity of dense liquids to this case of strong confinement, thus offering a tentative explanation of the growth of viscosity and how it grows as the separation between the surfaces is decreased, and making additional predictions. An important, purely phenomenological, input to our theory is the assumption that confinement makes the bare viscosity tensor of the fluid uniaxial.

Tags

Users

  • @statphys23

Comments and Reviews