Abstract
We study the interrelation between microscopic fluctuations and dissipative
effects in electromagnetism on the slow macroscopic scales. The main conclusion
is that there are dissipative effects of rather different origin than the
Ohmic effects Jelić, H$u$tter and $O$ttinger, Phys. Rev. E 74, 041126 (2006). In order to arrive at this conclusion, the following idea serves as a starting point. The usual procedure for deriving the equations for macroscopic
electromagnetism consists of distinguishing between bound and unbound charges.
This separation, in turn, leads to a separation of the electric current into
contributions related to freely mobile charges, polarization, and
magnetization. All of these three quantities fluctuate around their averages.
In the spirit of a generalized fluctuation-dissipation theorem, one concludes
that with each of these fluctuations, there are also three corresponding
dissipative effects on the slow macroscopic scale. While the
time-self-correlation of the current of free charges gives rise to the Ohmic
resistance, the time-self-correlations of the other two current contributions
lead to distinct irreversible contributions in the macroscopic electromagnetic
equations. This heuristic argument is formalized by using the General Equation
for the Non-Equilibrium Reversible-Irreversible Coupling (GENERIC) framework,
which is equipped with a generalized fluctuation-dissipation relation,
describing the emergence of dissipative effects upon coarse-graining.
The dissipative effects distinct from the Ohmic contribution have also been
introduced by Liu and coworkers Phys. Rev. Lett. 70, 3580 (1993) and later
papers by identifying the driving forces towards equilibrium and then
employing the positivity of the entropy production rate. Such a procedure
for formulating constitutive assumptions comes with certain parameters,
the transport coefficients, for which only certain positivity conditions
are known. While we reproduce the structure of all of Lius terms, we can
further illuminate the physics behind the new transport coefficients in
terms of microscopic fluctuations, and the self-correlations between them.
In this way, our procedure indicates how microscopic simulations can be
employed to extract those new transport coefficients, thereby rendering
the constitutive relations material specific.
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