Article,
Effect of relative humidity on OH uptake by surfaces of atmospheric importance
Journal of Physical Chemistry A, 112 (30): 6968--6977 (July 2008)330FX Times Cited:0 Cited References Count:74.
DOI: Doi 10.1021/Jp8012317
Abstract
An experimental study of the dependence of the OH uptake coefficient gamma(OH) over a relative humidity of 0-48% was carried out at 100 Torr and room temperature, using a differential bead-filled flow tube coupled to a high-pressure chemical ionization mass spectrometer. Various organic (paraffin wax, pyrene, glutaric acid, and soot) and inorganic (NaCl, KCl, MgCl2, CaCl2, Na2SO4, and sea salt) surfaces served as proxies for tropospheric aerosols. A virtual cylindrical flow tube approximation and a surface coating dilution technique were successfully employed in the study, which included measurements of high radical uptake with an initial probability of near unity. For inorganic salts, the effect of water vapor, enhancement or inhibition of gamma(OH), was found to be dependent on the blocking of anions and changes in surface pH. Although OH uptake by NaCl, the major component of sea-salt aerosols, is weakly dependent on water vapor, it is enhanced by a factor of similar to 2 for MgCl2 and determines the net relative humidity dependence of the radical uptake on sea salt, which is enhanced by a factor of similar to 4. For the organic surfaces studied, the enhancement effect of a factor 4 was also observed only for a hydrophilic organic surface, namely, glutaric acid. Results of the uptake studies suggest that the effect of relative humidity is important and should be accounted for in atmospheric modeling of tropospheric aerosol chemistry.
