Article,
STRUCTURAL, THEORETICAL, AND SPECTROSCOPIC STUDY OF MERCURY(II) COMPLEXES OF TWO NEW UNSYMMETRIC PHOSPHORUS YLIDES
S. Sabounchei, M. Panahimehr, S. Salehzadeh, M. Bayat, H. Khavasi, and D. Morales-Morales.PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, 188 (12): 1743-1758 (December 2013)
DOI: {10.1080/10426507.2013.779274}
Abstract
The reaction of Ph2PCH2PPh2 (dppm) with 4-methylphenacyl bromide and
2-(bromoacetyl)naphthalene in chloroform produce the new phosphonium
salts Ph2PCH2PPh2CH2C(O)C6H4MeBr (1) and
Ph2PCH2PPh2CH2C(O)C10H7Br (2). Further, by reaction of the
monophosphonium salts of dppm with the strong base Et3N the
corresponding bidentate phosphorus ylides, Ph2PCH2P(Ph)(2) =
C(H)C(O)C6H4Me (3) and Ph2PCH2P(Ph)(2) = C(H)C(O)C10H7 (4) were
obtained. The reaction of these ligands with mercury(II) halides in dry
methanol led to the formation of the mononuclear complexes
\HgX2(Ph2PCH2PPh2C(H)C(O)C6H4Me)\ X = Cl (5), Br (6), and I
(7) and \HgX2(Ph2PCH2PPh2C(H)C(O)C10H7)\ X = Cl (8), Br (9),
and I (10). Characterization of the obtained compounds was performed by
elemental analysis, IR, H-1, P-31, and C-13 NMR spectra. The structure
of compounds 3 and 10 are unequivocally determined by single crystal
X-ray diffraction techniques. X-ray analysis of 10 reveals the presence
of mononuclear complex containing Hg atom in a distorted tetrahedral
environment. In all complexes, the title ylides are coordinated through
the ylidic carbon and the phosphine phosphorus. Computational studies on
ligand 4 and complexes 8, 9, and 10 at DFT (B3LYP) level of theory are
also reported. It was shown that the formation of P,C-coordinated 1+1
complex 10 is energetically more favored than corresponding
P,P-coordinated 1+2 product. Supplemental materials are available for
this article. Go to the publisher's online edition of Phosphorus,
Sulfur, and Silicon and the Related Elements to view the following free
supplemental files: Additional figures
- BibTeX key
- ISI:000325124700007
- entry type
- article
- address
- 4 PARK SQUARE, MILTON PARK, ABINGDON OX14 4RN, OXON, ENGLAND
- year
- 2013
- month
- DEC 1
- journal
- PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS
- number
- 12
- pages
- 1743-1758
- publisher
- TAYLOR & FRANCIS LTD
- volume
- 188
- type
- Article
- author-email
- jsabounchei@yahoo.co.uk
- research-areas
- Chemistry
- language
- English
- eissn
- 1563-5325
- funding-text
- We are grateful to the Bu-Ali Sina University for a grant and Mr. Zebarjadian for recording the NMR spectra. Mehdi Bayat thanks the Marburg University of Germany for their support for doing the computation during his academic visit.
- researcherid-numbers
- Morales-Morales, David/A-1515-2008
- funding-acknowledgement
- Bu-Ali Sina University
- times-cited
- 4
- cited-references
- AbuGnim C, 1996, J ORGANOMET CHEM, V516, P235, DOI 10.1016/0022-328X(96)06137-2. BARBARO P, 1994, INORG CHEM, V33, P6163, DOI 10.1021/ic00104a029. Bebout DC, 1998, INORG CHEM, V37, P2952, DOI 10.1021/ic971499+. BECKE AD, 1993, J CHEM PHYS, V98, P5648, DOI 10.1063/1.464913. Belluco U, 1998, J ORGANOMET CHEM, V557, P37, DOI 10.1016/S0022-328X(97)00733-X. Bokach NA, 2003, INORG CHEM, V42, P3602, DOI 10.1021/ic034086j. Cadogan J. I. G., 1979, ORGANOPHOSPHORUS REA, V155. Christau H., 1994, J CHEM REV, V94, P1299. Ebrahim MM, 2007, POLYHEDRON, V26, P3491, DOI 10.1016/j.poly.2007.03.059. Ebrahim MM, 2007, POLYHEDRON, V26, P1277, DOI 10.1016/j.poly.2006.10.030. Ebrahim MM, 2009, J ORGANOMET CHEM, V694, P643, DOI 10.1016/j.jorganchem.2008.11.051. Effendy, 2004, INORG CHIM ACTA, V357, P1523, DOI 10.1016/j.ica.2003.11.010. Engle R., 1988, SYNTHESIS CARBON PHO. FALTH L, 1976, CHEM SCRIPTA, V9, P71. Falvello LR, 1998, INORG CHEM, V37, P6007, DOI 10.1021/ic980392z. Falvello LR, 2003, INORG CHIM ACTA, V347, P75, DOI 10.1016/S0020-1693(02)01448-2. Falvello LR, 2000, INORG CHEM, V39, P2957, DOI 10.1021/ic990923z. Frisch M. J., 2003, GAUSSIAN 03 REVISION. Grushin VV, 2004, CHEM REV, V104, P1629, DOI 10.1021/cr030026j. Jian FF, 2005, STRUCT CHEM, V16, P469, DOI 10.1007/s11224-005-4331-6. KALYANASUNDARI M, 1995, J ORGANOMET CHEM, V491, P103, DOI 10.1016/0022-328X(94)05217-Y. Karami K, 2010, J COORD CHEM, V63, P3688, DOI 10.1080/00958972.2010.515213. Karami K, 2009, J COORD CHEM, V62, P2949, DOI 10.1080/00958970902980529. KASKA WC, 1983, COORDIN CHEM REV, V48, P1, DOI 10.1016/0010-8545(83)85001-2. Kolodiazhnyi OI, 1996, TETRAHEDRON, V52, P1855, DOI 10.1016/0040-4020(95)00433-5. Kubicki M, 2001, POLYHEDRON, V20, P2179, DOI 10.1016/S0277-5387(01)00827-0. LEE CT, 1988, PHYS REV B, V37, P785, DOI 10.1103/PhysRevB.37.785. LIN IJB, 1990, J CHEM SOC DALTON, P2509, DOI 10.1039/dt9900002509. MARYANOFF BE, 1989, CHEM REV, V89, P863, DOI 10.1021/cr00094a007. Navarro R, 1999, J CHEM SOC DALTON, P4111, DOI 10.1039/a906116i. Oliveira E, 2011, INORG CHIM ACTA, V366, P154, DOI 10.1016/j.ica.2010.10.025. OOSAWA Y, 1976, J ORGANOMET CHEM, V122, P113, DOI 10.1016/S0022-328X(00)92752-9. Sabounchei SJ, 2008, POLYHEDRON, V27, P2015, DOI 10.1016/j.poly.2008.03.009. Sabounchei SJ, 2008, J ORGANOMET CHEM, V693, P1975, DOI 10.1016/j.jorganchem.2008.02.025. Sabounchei SJ, 2013, J ORGANOMET CHEM, V723, P207, DOI 10.1016/j.jorganchem.2012.10.004. Sabounchei SJ, 2010, INORG CHIM ACTA, V363, P3973, DOI 10.1016/j.ica.2010.07.072. Sabounchei SJ, 2010, INORG CHIM ACTA, V363, P3654, DOI 10.1016/j.ica.2010.05.004. Sabounchei SJ, 2010, HELV CHIM ACTA, V93, P1105. Sabounchei SJ, 2010, J ORGANOMET CHEM, V695, P1441, DOI 10.1016/j.jorganchem.2010.02.029. Sabounchei SJ, 2010, INORG CHIM ACTA, V363, P1254, DOI 10.1016/j.ica.2010.01.024. Sabounchei SJ, 2009, INORG CHIM ACTA, V362, P105, DOI 10.1016/j.ica.2008.03.015. Sabounchei SJ, 2006, PHOSPHORUS SULFUR, V181, P1331, DOI 10.1080/10426500500326974. Sabounchei SJ, 2004, PHOSPHORUS SULFUR, V179, P2029, DOI 10.1080/10426500490473582. Sabounchei SJ, 2003, PHOSPHORUS SULFUR, V178, P1559, DOI 10.1080/10426500390212960. Sabounchei S. J., 2010, XRAY STRUCT ANAL ONL, V26, P35, DOI 10.2116/xraystruct.26.35. Samanta T, 2011, INORG CHIM ACTA, V375, P271, DOI 10.1016/j.ica.2011.05.017. Saravanabharathi D, 2003, P INDIAN AS-CHEM SCI, V115, P741. Sbovata SM, 2008, INORG CHIM ACTA, V361, P3177, DOI 10.1016/j.ica.2007.10.055. SCHMIDBAUR H, 1983, ANGEW CHEM INT EDIT, V22, P907, DOI 10.1002/anie.198309071. Sheldrick GM, 2008, ACTA CRYSTALLOGR A, V64, P112, DOI 10.1107/S0108767307043930. Spannenberg A, 2000, ORGANOMETALLICS, V19, P3991, DOI 10.1021/om000429z. Stoe Cie, 2005, X AREA X RED. Stoe Cie, 2005, X STEP32. Urriolabeitia EP, 2008, DALTON T, P5673, DOI 10.1039/b806787b. USON R, 1987, J ORGANOMET CHEM, V334, P389, DOI 10.1016/0022-328X(87)80101-8. VICENTE J, 1994, ORGANOMETALLICS, V13, P1243, DOI 10.1021/om00016a029. VICENTE J, 1992, J CHEM SOC CHEM COMM, P915, DOI 10.1039/c39920000915. VICENTE J, 1991, J CHEM SOC CHEM COMM, P1730, DOI 10.1039/c39910001730. VICENTE J, 1987, J ORGANOMET CHEM, V331, P409, DOI 10.1016/0022-328X(87)80012-8. VICENTE J, 1991, J CHEM SOC DALTON, P2579, DOI 10.1039/dt9910002579. Wagner G, 2001, INORG CHEM, V40, P1683, DOI 10.1021/ic000769c. WEGMAN RW, 1987, J CHEM SOC CHEM COMM, P1891, DOI 10.1039/c39870001891. Wittig G., 1980, ANGEW CHEM, V92, P671, DOI 10.1002/ange.19800920904.
- issn
- 1042-6507
- affiliation
- Sabounchei, SJ (Reprint Author), Univ Bu Ali Sina, Fac Chem, Hamadan 65174, Iran. Sabounchei, Seyyed Javad; Panahimehr, Mohammad; Salehzadeh, Sadegh; Bayat, Mehdi, Univ Bu Ali Sina, Fac Chem, Hamadan 65174, Iran. Khavasi, Hamid Reza, Shahid Beheshti Univ, Dept Chem, GC, Tehran 1983963113, Iran. Morales-Morales, David, Univ Nacl Autonoma Mexico, Inst Quim, Mexico City 04510, DF, Mexico.
- orcid-numbers
- Morales-Morales, David/0000-0002-7984-1819
- usage-count-since-2013
- 10
- doc-delivery-number
- 227PB
- web-of-science-categories
- Chemistry, Inorganic & Nuclear; Chemistry, Organic
- usage-count-last-180-days
- 0
- number-of-cited-references
- 63
- journal-iso
- Phosphorus Sulfur Silicon Relat. Elem.
- keywords-plus
- RAY CRYSTAL-STRUCTURE; PD-II COMPLEXES; PALLADIUM(II) COMPLEXES; SILVER(I) COMPLEXES; MOLECULAR-STRUCTURE; PD(0) COMPLEXES; LIGANDS; COORDINATION; HALIDES; ACTIVATION
- unique-id
- ISI:000325124700007
- DOI
- 10.1080/10426507.2013.779274
Tags
- complexes;
- computational
- crystal
- halides
- mercury(ii)
- multinuclear
- nmr
- structure;
- studies}
- study;
- x-ray
- ylide;
- {phosphorus
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%1 ISI:000325124700007
%A Sabounchei, Seyyed Javad
%A Panahimehr, Mohammad
%A Salehzadeh, Sadegh
%A Bayat, Mehdi
%A Khavasi, Hamid Reza
%A Morales-Morales, David
%C 4 PARK SQUARE, MILTON PARK, ABINGDON OX14 4RN, OXON, ENGLAND
%D 2013
%I TAYLOR & FRANCIS LTD
%J PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS
%K NMR X-ray complexes; computational crystal halides mercury(II) multinuclear structure; studies} study; ylide; {Phosphorus
%N 12
%P 1743-1758
%R 10.1080/10426507.2013.779274
%T STRUCTURAL, THEORETICAL, AND SPECTROSCOPIC STUDY OF MERCURY(II)
COMPLEXES OF TWO NEW UNSYMMETRIC PHOSPHORUS YLIDES
%V 188
%X The reaction of Ph2PCH2PPh2 (dppm) with 4-methylphenacyl bromide and
2-(bromoacetyl)naphthalene in chloroform produce the new phosphonium
salts Ph2PCH2PPh2CH2C(O)C6H4MeBr (1) and
Ph2PCH2PPh2CH2C(O)C10H7Br (2). Further, by reaction of the
monophosphonium salts of dppm with the strong base Et3N the
corresponding bidentate phosphorus ylides, Ph2PCH2P(Ph)(2) =
C(H)C(O)C6H4Me (3) and Ph2PCH2P(Ph)(2) = C(H)C(O)C10H7 (4) were
obtained. The reaction of these ligands with mercury(II) halides in dry
methanol led to the formation of the mononuclear complexes
\HgX2(Ph2PCH2PPh2C(H)C(O)C6H4Me)\ X = Cl (5), Br (6), and I
(7) and \HgX2(Ph2PCH2PPh2C(H)C(O)C10H7)\ X = Cl (8), Br (9),
and I (10). Characterization of the obtained compounds was performed by
elemental analysis, IR, H-1, P-31, and C-13 NMR spectra. The structure
of compounds 3 and 10 are unequivocally determined by single crystal
X-ray diffraction techniques. X-ray analysis of 10 reveals the presence
of mononuclear complex containing Hg atom in a distorted tetrahedral
environment. In all complexes, the title ylides are coordinated through
the ylidic carbon and the phosphine phosphorus. Computational studies on
ligand 4 and complexes 8, 9, and 10 at DFT (B3LYP) level of theory are
also reported. It was shown that the formation of P,C-coordinated 1+1
complex 10 is energetically more favored than corresponding
P,P-coordinated 1+2 product. Supplemental materials are available for
this article. Go to the publisher's online edition of Phosphorus,
Sulfur, and Silicon and the Related Elements to view the following free
supplemental files: Additional figures
@article{ISI:000325124700007,
abstract = {{The reaction of Ph2PCH2PPh2 (dppm) with 4-methylphenacyl bromide and
2-(bromoacetyl)naphthalene in chloroform produce the new phosphonium
salts {[}Ph2PCH2PPh2CH2C(O)C6H4Me]Br (1) and
{[}Ph2PCH2PPh2CH2C(O)C10H7]Br (2). Further, by reaction of the
monophosphonium salts of dppm with the strong base Et3N the
corresponding bidentate phosphorus ylides, Ph2PCH2P(Ph)(2) =
C(H)C(O)C6H4Me (3) and Ph2PCH2P(Ph)(2) = C(H)C(O)C10H7 (4) were
obtained. The reaction of these ligands with mercury(II) halides in dry
methanol led to the formation of the mononuclear complexes
\{HgX2{[}(Ph2PCH2PPh2C(H)C(O)C6H4Me)]\} {[}X = Cl (5), Br (6), and I
(7)] and \{HgX2{[}(Ph2PCH2PPh2C(H)C(O)C10H7)]\} {[}X = Cl (8), Br (9),
and I (10)]. Characterization of the obtained compounds was performed by
elemental analysis, IR, H-1, P-31, and C-13 NMR spectra. The structure
of compounds 3 and 10 are unequivocally determined by single crystal
X-ray diffraction techniques. X-ray analysis of 10 reveals the presence
of mononuclear complex containing Hg atom in a distorted tetrahedral
environment. In all complexes, the title ylides are coordinated through
the ylidic carbon and the phosphine phosphorus. Computational studies on
ligand 4 and complexes 8, 9, and 10 at DFT (B3LYP) level of theory are
also reported. It was shown that the formation of P,C-coordinated 1+1
complex 10 is energetically more favored than corresponding
P,P-coordinated 1+2 product. {[}Supplemental materials are available for
this article. Go to the publisher's online edition of Phosphorus,
Sulfur, and Silicon and the Related Elements to view the following free
supplemental files: Additional figures]}},
added-at = {2017-05-10T15:29:29.000+0200},
address = {{4 PARK SQUARE, MILTON PARK, ABINGDON OX14 4RN, OXON, ENGLAND}},
affiliation = {{Sabounchei, SJ (Reprint Author), Univ Bu Ali Sina, Fac Chem, Hamadan 65174, Iran.
Sabounchei, Seyyed Javad; Panahimehr, Mohammad; Salehzadeh, Sadegh; Bayat, Mehdi, Univ Bu Ali Sina, Fac Chem, Hamadan 65174, Iran.
Khavasi, Hamid Reza, Shahid Beheshti Univ, Dept Chem, GC, Tehran 1983963113, Iran.
Morales-Morales, David, Univ Nacl Autonoma Mexico, Inst Quim, Mexico City 04510, DF, Mexico.}},
author = {Sabounchei, Seyyed Javad and Panahimehr, Mohammad and Salehzadeh, Sadegh and Bayat, Mehdi and Khavasi, Hamid Reza and Morales-Morales, David},
author-email = {{jsabounchei@yahoo.co.uk}},
biburl = {https://www.bibsonomy.org/bibtex/2418f3f54e072dafe1007dc7a551eedea/hkhavasi},
cited-references = {{AbuGnim C, 1996, J ORGANOMET CHEM, V516, P235, DOI 10.1016/0022-328X(96)06137-2.
BARBARO P, 1994, INORG CHEM, V33, P6163, DOI 10.1021/ic00104a029.
Bebout DC, 1998, INORG CHEM, V37, P2952, DOI 10.1021/ic971499+.
BECKE AD, 1993, J CHEM PHYS, V98, P5648, DOI 10.1063/1.464913.
Belluco U, 1998, J ORGANOMET CHEM, V557, P37, DOI 10.1016/S0022-328X(97)00733-X.
Bokach NA, 2003, INORG CHEM, V42, P3602, DOI 10.1021/ic034086j.
Cadogan J. I. G., 1979, ORGANOPHOSPHORUS REA, V155.
Christau H., 1994, J CHEM REV, V94, P1299.
Ebrahim MM, 2007, POLYHEDRON, V26, P3491, DOI 10.1016/j.poly.2007.03.059.
Ebrahim MM, 2007, POLYHEDRON, V26, P1277, DOI 10.1016/j.poly.2006.10.030.
Ebrahim MM, 2009, J ORGANOMET CHEM, V694, P643, DOI 10.1016/j.jorganchem.2008.11.051.
Effendy, 2004, INORG CHIM ACTA, V357, P1523, DOI 10.1016/j.ica.2003.11.010.
Engle R., 1988, SYNTHESIS CARBON PHO.
FALTH L, 1976, CHEM SCRIPTA, V9, P71.
Falvello LR, 1998, INORG CHEM, V37, P6007, DOI 10.1021/ic980392z.
Falvello LR, 2003, INORG CHIM ACTA, V347, P75, DOI 10.1016/S0020-1693(02)01448-2.
Falvello LR, 2000, INORG CHEM, V39, P2957, DOI 10.1021/ic990923z.
Frisch M. J., 2003, GAUSSIAN 03 REVISION.
Grushin VV, 2004, CHEM REV, V104, P1629, DOI 10.1021/cr030026j.
Jian FF, 2005, STRUCT CHEM, V16, P469, DOI 10.1007/s11224-005-4331-6.
KALYANASUNDARI M, 1995, J ORGANOMET CHEM, V491, P103, DOI 10.1016/0022-328X(94)05217-Y.
Karami K, 2010, J COORD CHEM, V63, P3688, DOI 10.1080/00958972.2010.515213.
Karami K, 2009, J COORD CHEM, V62, P2949, DOI 10.1080/00958970902980529.
KASKA WC, 1983, COORDIN CHEM REV, V48, P1, DOI 10.1016/0010-8545(83)85001-2.
Kolodiazhnyi OI, 1996, TETRAHEDRON, V52, P1855, DOI 10.1016/0040-4020(95)00433-5.
Kubicki M, 2001, POLYHEDRON, V20, P2179, DOI 10.1016/S0277-5387(01)00827-0.
LEE CT, 1988, PHYS REV B, V37, P785, DOI 10.1103/PhysRevB.37.785.
LIN IJB, 1990, J CHEM SOC DALTON, P2509, DOI 10.1039/dt9900002509.
MARYANOFF BE, 1989, CHEM REV, V89, P863, DOI 10.1021/cr00094a007.
Navarro R, 1999, J CHEM SOC DALTON, P4111, DOI 10.1039/a906116i.
Oliveira E, 2011, INORG CHIM ACTA, V366, P154, DOI 10.1016/j.ica.2010.10.025.
OOSAWA Y, 1976, J ORGANOMET CHEM, V122, P113, DOI 10.1016/S0022-328X(00)92752-9.
Sabounchei SJ, 2008, POLYHEDRON, V27, P2015, DOI 10.1016/j.poly.2008.03.009.
Sabounchei SJ, 2008, J ORGANOMET CHEM, V693, P1975, DOI 10.1016/j.jorganchem.2008.02.025.
Sabounchei SJ, 2013, J ORGANOMET CHEM, V723, P207, DOI 10.1016/j.jorganchem.2012.10.004.
Sabounchei SJ, 2010, INORG CHIM ACTA, V363, P3973, DOI 10.1016/j.ica.2010.07.072.
Sabounchei SJ, 2010, INORG CHIM ACTA, V363, P3654, DOI 10.1016/j.ica.2010.05.004.
Sabounchei SJ, 2010, HELV CHIM ACTA, V93, P1105.
Sabounchei SJ, 2010, J ORGANOMET CHEM, V695, P1441, DOI 10.1016/j.jorganchem.2010.02.029.
Sabounchei SJ, 2010, INORG CHIM ACTA, V363, P1254, DOI 10.1016/j.ica.2010.01.024.
Sabounchei SJ, 2009, INORG CHIM ACTA, V362, P105, DOI 10.1016/j.ica.2008.03.015.
Sabounchei SJ, 2006, PHOSPHORUS SULFUR, V181, P1331, DOI 10.1080/10426500500326974.
Sabounchei SJ, 2004, PHOSPHORUS SULFUR, V179, P2029, DOI 10.1080/10426500490473582.
Sabounchei SJ, 2003, PHOSPHORUS SULFUR, V178, P1559, DOI 10.1080/10426500390212960.
Sabounchei S. J., 2010, XRAY STRUCT ANAL ONL, V26, P35, DOI 10.2116/xraystruct.26.35.
Samanta T, 2011, INORG CHIM ACTA, V375, P271, DOI 10.1016/j.ica.2011.05.017.
Saravanabharathi D, 2003, P INDIAN AS-CHEM SCI, V115, P741.
Sbovata SM, 2008, INORG CHIM ACTA, V361, P3177, DOI 10.1016/j.ica.2007.10.055.
SCHMIDBAUR H, 1983, ANGEW CHEM INT EDIT, V22, P907, DOI 10.1002/anie.198309071.
Sheldrick GM, 2008, ACTA CRYSTALLOGR A, V64, P112, DOI 10.1107/S0108767307043930.
Spannenberg A, 2000, ORGANOMETALLICS, V19, P3991, DOI 10.1021/om000429z.
Stoe Cie, 2005, X AREA X RED.
Stoe Cie, 2005, X STEP32.
Urriolabeitia EP, 2008, DALTON T, P5673, DOI 10.1039/b806787b.
USON R, 1987, J ORGANOMET CHEM, V334, P389, DOI 10.1016/0022-328X(87)80101-8.
VICENTE J, 1994, ORGANOMETALLICS, V13, P1243, DOI 10.1021/om00016a029.
VICENTE J, 1992, J CHEM SOC CHEM COMM, P915, DOI 10.1039/c39920000915.
VICENTE J, 1991, J CHEM SOC CHEM COMM, P1730, DOI 10.1039/c39910001730.
VICENTE J, 1987, J ORGANOMET CHEM, V331, P409, DOI 10.1016/0022-328X(87)80012-8.
VICENTE J, 1991, J CHEM SOC DALTON, P2579, DOI 10.1039/dt9910002579.
Wagner G, 2001, INORG CHEM, V40, P1683, DOI 10.1021/ic000769c.
WEGMAN RW, 1987, J CHEM SOC CHEM COMM, P1891, DOI 10.1039/c39870001891.
Wittig G., 1980, ANGEW CHEM, V92, P671, DOI 10.1002/ange.19800920904.}},
doc-delivery-number = {{227PB}},
doi = {{10.1080/10426507.2013.779274}},
eissn = {{1563-5325}},
funding-acknowledgement = {{Bu-Ali Sina University}},
funding-text = {{We are grateful to the Bu-Ali Sina University for a grant and Mr.
Zebarjadian for recording the NMR spectra. Mehdi Bayat thanks the
Marburg University of Germany for their support for doing the
computation during his academic visit.}},
interhash = {b922f17328129ad81ef4a5b9983fe8c5},
intrahash = {418f3f54e072dafe1007dc7a551eedea},
issn = {{1042-6507}},
journal = {{PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS}},
journal-iso = {{Phosphorus Sulfur Silicon Relat. Elem.}},
keywords = {NMR X-ray complexes; computational crystal halides mercury(II) multinuclear structure; studies} study; ylide; {Phosphorus},
keywords-plus = {{RAY CRYSTAL-STRUCTURE; PD-II COMPLEXES; PALLADIUM(II) COMPLEXES;
SILVER(I) COMPLEXES; MOLECULAR-STRUCTURE; PD(0) COMPLEXES; LIGANDS;
COORDINATION; HALIDES; ACTIVATION}},
language = {{English}},
month = {{DEC 1}},
number = {{12}},
number-of-cited-references = {{63}},
orcid-numbers = {{Morales-Morales, David/0000-0002-7984-1819}},
pages = {{1743-1758}},
publisher = {{TAYLOR \& FRANCIS LTD}},
research-areas = {{Chemistry}},
researcherid-numbers = {{Morales-Morales, David/A-1515-2008}},
times-cited = {{4}},
timestamp = {2017-05-10T15:29:29.000+0200},
title = {{STRUCTURAL, THEORETICAL, AND SPECTROSCOPIC STUDY OF MERCURY(II)
COMPLEXES OF TWO NEW UNSYMMETRIC PHOSPHORUS YLIDES}},
type = {{Article}},
unique-id = {{ISI:000325124700007}},
usage-count-last-180-days = {{0}},
usage-count-since-2013 = {{10}},
volume = {{188}},
web-of-science-categories = {{Chemistry, Inorganic \& Nuclear; Chemistry, Organic}},
year = {{2013}}
}